Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry
L Buglioni, F Raymenants, A Slattery… - Chemical …, 2021 - ACS Publications
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry
Z Liu, P Sivaguru, G Zanoni, X Bi - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Over recent decades, N-sulfonylhydrazones have attracted significant attention
in academic and industrial contexts owing to their ease of preparation, versatile reactivity …
in academic and industrial contexts owing to their ease of preparation, versatile reactivity …
How to approach flow chemistry
Flow chemistry is a widely explored technology whose intrinsic features both facilitate and
provide reproducible access to a broad range of chemical processes that are otherwise …
provide reproducible access to a broad range of chemical processes that are otherwise …
Thermal stability and explosive hazard assessment of diazo compounds and diazo transfer reagents
SP Green, KM Wheelhouse, AD Payne… - … process research & …, 2019 - ACS Publications
Despite their wide use in academia as metal-carbene precursors, diazo compounds are
often avoided in industry owing to concerns over their instability, exothermic decomposition …
often avoided in industry owing to concerns over their instability, exothermic decomposition …
Recent developments in photochemical reactions of diazo compounds
ŁW Ciszewski, K Rybicka-Jasińska… - Organic & Biomolecular …, 2019 - pubs.rsc.org
Diazo compounds are among the most important building blocks in organic synthesis.
Generally, their photoinitiated, thermal, or transition metal catalyzed decomposition yields …
Generally, their photoinitiated, thermal, or transition metal catalyzed decomposition yields …
Blue‐Light‐Induced Carbene‐Transfer Reactions of Diazoalkanes
R Hommelsheim, Y Guo, Z Yang… - Angewandte Chemie …, 2019 - Wiley Online Library
Carbenes are very important reactive intermediates to access a variety of complex
molecules and are applied widely in organic synthesis and drug discovery. Typically, their …
molecules and are applied widely in organic synthesis and drug discovery. Typically, their …
Emerging trends in flow chemistry and applications to the pharmaceutical industry
AR Bogdan, AW Dombrowski - Journal of medicinal chemistry, 2019 - ACS Publications
The field of flow chemistry has garnered considerable attention over the past 2 decades.
This Perspective highlights many recent advances in the field of flow chemistry and …
This Perspective highlights many recent advances in the field of flow chemistry and …
The concept of chemical generators: on-site on-demand production of hazardous reagents in continuous flow
Conspectus In recent years, a steadily growing number of chemists, from both academia and
industry, have dedicated their research to the development of continuous flow processes …
industry, have dedicated their research to the development of continuous flow processes …
Flow biocatalysis: A challenging alternative for the synthesis of APIs and natural compounds
Biocatalysts represent an efficient, highly selective and greener alternative to metal catalysts
in both industry and academia. In the last two decades, the interest in biocatalytic …
in both industry and academia. In the last two decades, the interest in biocatalytic …
Pushing the boundaries of C–H bond functionalization chemistry using flow technology
C–H functionalization chemistry is one of the most vibrant research areas within synthetic
organic chemistry. While most researchers focus on the development of small-scale batch …
organic chemistry. While most researchers focus on the development of small-scale batch …