Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …
strategies that is currently attracting tremendous attention with the aim to provide alternative …
Weakly Coordinating Directing Groups for Ruthenium (II)‐Catalyzed C H Activation
S De Sarkar, W Liu, SI Kozhushkov… - … Synthesis & Catalysis, 2014 - Wiley Online Library
Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic
acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in …
acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in …
Recent developments in ruthenium-catalyzed C–H arylation: Array of mechanistic manifolds
Functionalized biaryl-containing motifs are among the most valuable synthetic scaffolds in
organic chemistry with wide ranging commercial applications in pharmaceuticals, functional …
organic chemistry with wide ranging commercial applications in pharmaceuticals, functional …
Cross dehydrogenative coupling via base-promoted homolytic aromatic substitution (BHAS): synthesis of fluorenones and xanthones
Cross dehydrogenative coupling reactions occurring via base-promoted homolytic aromatic
substitutions (BHASs) are reported. Fluorenones and xanthones are readily prepared via …
substitutions (BHASs) are reported. Fluorenones and xanthones are readily prepared via …
Iron-Catalyzed C(sp2)–H Bond Functionalization with Organoboron Compounds
We report here that an iron-catalyzed directed C–H functionalization reaction allows the
coupling of a variety of aromatic, heteroaromatic, and olefinic substrates with alkenyl and …
coupling of a variety of aromatic, heteroaromatic, and olefinic substrates with alkenyl and …
Synthesis of fluorenones from benzaldehydes and aryl iodides: dual C–H functionalizations using a transient directing group
The first synthesis of substituted fluorenones directly from benzaldehydes and aryl iodides
via a Pd (II)-catalyzed C (sp2)–H functionalization cascade is reported. Featuring anthranilic …
via a Pd (II)-catalyzed C (sp2)–H functionalization cascade is reported. Featuring anthranilic …
Recent advances in C–H bond functionalization with ruthenium-based catalysts
KS Singh - Catalysts, 2019 - mdpi.com
The past decades have witnessed rapid development in organic synthesis via catalysis,
particularly the reactions through C–H bond functionalization. Transition metals such as Pd …
particularly the reactions through C–H bond functionalization. Transition metals such as Pd …
Aromatic C–H coupling with hindered arylboronic acids by Pd/Fe dual catalysts
K Yamaguchi, H Kondo, J Yamaguchi, K Itami - Chemical Science, 2013 - pubs.rsc.org
An aerobic oxidative coupling of arenes/alkenes with arylboronic acids (C–H/C–B coupling)
using catalytic Pd (II)–sulfoxide–oxazoline (sox) ligand and iron–phthalocyanine (FePc) has …
using catalytic Pd (II)–sulfoxide–oxazoline (sox) ligand and iron–phthalocyanine (FePc) has …
Amides as weak coordinating groups in proximal C–H bond activation
Site selectivity is an inherent challenge in C–H functionalization reactions. The most
intensively sought‐after approaches have involved the employment of Lewis‐basic …
intensively sought‐after approaches have involved the employment of Lewis‐basic …
Palladium‐Catalysed, Directed C H Coupling with Organometallics
Transition metal (TM)‐catalysed C H coupling using organometallic reagents is developing
into a distinct transformation area for the construction of carbon‐carbon (C C) bonds …
into a distinct transformation area for the construction of carbon‐carbon (C C) bonds …