Forging colloidal nanostructures via cation exchange reactions

L De Trizio, L Manna - Chemical reviews, 2016 - ACS Publications
Among the various postsynthesis treatments of colloidal nanocrystals that have been
developed to date, transformations by cation exchange have recently emerged as an …

Porous single‐crystal‐based inorganic semiconductor photocatalysts for energy production and environmental remediation: preparation, modification, and …

J Niu, J Albero, P Atienzar… - Advanced Functional …, 2020 - Wiley Online Library
Semiconductor photocatalytic and photovoltaic performance depends on crystallinity and
surface area to a large extent. One strategy that has recently emergyed to improve …

Synthesis of Bandgap‐tunable Transition Metal Sulfides through Gas‐phase Cation Exchange‐induced Topological Transformation

P Da, Y Zheng, Y Hu, Z Wu, H Zhao… - Angewandte Chemie …, 2023 - Wiley Online Library
Oriented synthesis of transition metal sulfides (TMSs) with controlled compositions and
crystal structures has long been promising for electronic devices and energy applications …

Determinants of crystal structure transformation of ionic nanocrystals in cation exchange reactions

Z Li, M Saruyama, T Asaka, Y Tatetsu, T Teranishi - Science, 2021 - science.org
Changes in the crystal system of an ionic nanocrystal during a cation exchange reaction are
unusual yet remain to be systematically investigated. In this study, chemical synthesis and …

Cation/anion exchange reactions toward the syntheses of upgraded nanostructures: principles and applications

X Li, M Ji, H Li, H Wang, M Xu, H Rong, J Wei, J Liu… - Matter, 2020 - cell.com
The last 5 years have witnessed rapid progress in the field of hybrid nanostructures toward
enhanced optical and electronic properties. On this topic, we focus on the relevant progress …

Cation exchange induced transformation of InP magic-sized clusters

JL Stein, MI Steimle, MW Terban, A Petrone… - Chemistry of …, 2017 - ACS Publications
Magic-sized clusters (MSCs) can provide valuable insight into the atomically precise
progression of semiconductor nanocrystal transformations. We report the conversion of an …

Influence of the ion coordination number on cation exchange reactions with copper telluride nanocrystals

R Tu, Y Xie, G Bertoni, A Lak, R Gaspari… - Journal of the …, 2016 - ACS Publications
Cu2–x Te nanocubes were used as starting seeds to access metal telluride nanocrystals by
cation exchanges at room temperature. The coordination number of the entering cations was …

Phosphine-induced phase transition in copper sulfide nanoparticles prior to initiation of a cation exchange reaction

BC Steimle, RW Lord, RE Schaak - Journal of the American …, 2020 - ACS Publications
Cation exchange reactions of colloidal copper sulfide nanoparticles are widely used to
produce derivative nanoparticles having unique compositions, metastable crystal structures …

Kinetic Analysis of the Cation Exchange in Nanorods from Cu2–xS to CuInS2: Influence of Djurleite's Phase Transition Temperature on the Mechanism

F Thiel, C Palencia, H Weller - ACS nano, 2023 - ACS Publications
In the syntheses of ternary I–III–VI2 compounds, such as CuInS2, it is often difficult to
balance three precursor reactivities to achieve the desired size, shape, and atomic …

Enhanced carrier transport in strongly coupled, epitaxially fused CdSe nanocrystal solids

Q Zhao, G Gouget, J Guo, S Yang, T Zhao… - Nano Letters, 2021 - ACS Publications
Strongly coupled, epitaxially fused colloidal nanocrystal (NC) solids are promising solution-
processable semiconductors to realize optoelectronic devices with high carrier mobilities …