Photochemical reactions are a key method to generate radical intermediates. Often under
these conditions no toxic reagents are necessary. During recent years, photo-redox catalytic …

O-Acyl oximes are versatile building blocks being widely applied in organic synthesis,
especially for N-heterocycle construction under transition metal catalysis. In the last decade …

There have been significant advancements in radical-mediated reactions through covalent-
based organocatalysis. Here, we present the generation of iminyl and amidyl radicals via N …

Owing to the inert nature of the pyridine ring and high activity of iminyl radicals, the reaction
between pyridine and iminyl radicals remains a significant challenge. In this paper, we …

The formation and use of iminyl radicals in novel and divergent hydroimination and
iminohydroxylation cyclization reactions has been accomplished through the design of a …

A unified strategy involving visible‐light‐induced iminyl‐radical formation has been
established for the construction of pyridines, quinolines, and phenanthridines from acyl …

An intermolecular, two‐component vicinal carboimination of alkenes has been
accomplished by energy transfer catalysis. Oxime esters of alkyl carboxylic acids were used …

The visible‐light‐promoted decarboxylation of α‐imino‐oxy propionic acids for the
generation of iminyl radicals has been accomplished through the use of Ir (dFCF3ppy) 2 …

An iron‐catalyzed coupling reaction of O‐acyloximes and O‐benzoyl amidoximes with silyl
enol ethers is reported. The protocol provides access to functionalized pyrroles, 1, 6 …

A plethora of drug molecules and agrochemicals contain the sulfonamide functional group.
However, sulfonamides are seldom viewed as synthetically useful functional groups. To …