Metal chalcophosphates are chemically and structurally diverse due to the various
connective ways of phosphorus-sulfur/selenium anionic groups. Rare earth metals have …

Inspired by the ongoing search for new superionic lithium thiophosphates for use in solid-
state batteries, we present the synthesis and structural characterization of Li2P2S6, a novel …

Inspired by reports of redox active interphases in all-solid-state batteries employing fast
conducting lithium thiophosphate solid-state electrolytes, we investigated the compositional …

Three thiophosphates including noncentrosymmetric Na6Pb3P4S16 and centrosymmetric
K2MIIP2S6 (MII= Mg and Zn) were successfully synthesized in vacuum-sealed silica tubes …

Flame-melting rapid-cooling reactions were used to synthesize a number of pure phases of
the Cs2MIIMIV3Q8 family (MII= Mg, Zn, Cd, Hg; MIV= Ge, Sn; Q= S, Se, Te) whereas the …

The performance of nanocomposite electrodes prepared by controlled ball-milling of TiS2
and a Li2S–P2S5 solid electrolyte (SE) for all-solid-state lithium batteries is investigated …

Thiophosphate compounds have been studied extensively in the past for their rich structural
variations and for a large variety of interesting properties. Here, we report 11 new phases …

As the ongoing research in cation-conductive thiophosphates attracted attention especially
for the Li+-ion conducting materials, their great structural variety and potential application …

To determine the influence of the lanthanide size on the structures and properties of
thiophosphates, a thiophosphate series containing different lanthanides was synthesized via …

Inorganic phosphosulfides—materials containing phosphorus, sulfur, and at least one metal—
are a vast and chemically-versatile family of materials. Benefiting from a wide range of …