The main contributions in the field of first-row transition-metal-catalyzed (base-metal-
catalyzed) carbonylative transformations have been summarized and discussed. The …

Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Late-stage functionalization of C–H bonds (C–H LSF) can provide a straightforward
approach to the efficient synthesis of functionalized complex molecules. However, C–H LSF …

Rhodium (III)-catalyzed direct functionalization of C–H bonds under oxidative conditions
leading to C–C, C–N, and C–O bond formation is reviewed. Various arene substrates …

The use of coordinating moieties as directing groups for the functionalisation of aromatic
carbon–hydrogen (C–H) bonds has become an efficient strategy for the selective …

Palladium-catalyzed coupling reactions have become a powerful tool in organic synthesis. 1
Today, there are numerous applications of palladium catalysts in the preparation of …

In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed
oxidative coupling via C–H functionalization of aromatic, benzylic and allylic C–H bonds …

Carbonyl derivatives widely exist in pharmaceuticals, agricultural chemicals, materials, and
natural products. Developing novel, efficient, and green carbonylation methods represent …

Oxidative carbonylation reactions have attracted broad interest from both academia and
industry in recent years. Enormous efforts have gone into the syntheses of carbonate and …

Chiral amines are widely used as catalysts in asymmetric synthesis to activate carbonyl
groups for α-functionalization. Carbonyl catalysis reverses that strategy by using a carbonyl …