Recent advances in polyoxometalate-based single-molecule magnets

ZX Yang, F Gong, D Lin, Y Huo - Coordination Chemistry Reviews, 2023 - Elsevier
Single-molecule magnets (SMMs) have attracted increasing attention in recent years due to
the potentially applicable in high-density information storage and spintronic devices. There …

Methods and models of theoretical calculation for single-molecule magnets

QC Luo, YZ Zheng - Magnetochemistry, 2021 - mdpi.com
Theoretical calculation plays an important role in the emerging field of single-molecule
magnets (SMMs). It can not only explain experimental phenomena but also provide synthetic …

Enriching lanthanide single-ion magnetism through symmetry and axiality

SK Gupta, R Murugavel - Chemical Communications, 2018 - pubs.rsc.org
Rapidly growing modern information technology demands energy and cost efficient tools
that can efficiently store and process a large amount of data. However, the miniaturization …

[HTML][HTML] Improving the single-molecule magnet properties of two pentagonal bipyramidal Dy 3+ compounds by the introduction of both electron-withdrawing and …

L Zhu, Y Dong, B Yin, P Ma, D Li - Dalton Transactions, 2021 - pubs.rsc.org
Two mononuclear Dy3+ compounds [Dy (bmbpen-F) X](X= Cl, 1; Br, 2) with a pentagonal
bipyramidal (PBP) geometry were obtained from N, N′-bis-(5-methyl-2-hydroxybenzyl)-N …

Experimental and Theoretical Interpretation on the Magnetic Behavior in a Series of Pentagonal‐Bipyramidal DyIII Single‐Ion Magnets

M Li, H Wu, Q Yang, H Ke, B Yin, Q Shi… - … A European Journal, 2017 - Wiley Online Library
Taking advantage of the steric hindrance and charge‐driving effects, four air‐stable
pentagonal bipyramidal mononuclear DyIII compounds were hydrothermally synthesized …

Novel stable ytterbium acetylacetonate–quinaldinate complexes as single-molecule magnets and surprisingly efficient luminophores

AV Gavrikov, AB Ilyukhin, IV Taydakov, MT Metlin… - Dalton …, 2023 - pubs.rsc.org
The first Yb complexes comprising a quinoline-2-carboxylate (quinaldinate, Q−) ligand,
namely 1D-polymeric [Yb (acac) 2 (Q)] n (1, acac− is the acetylacetonate (pentane-2, 4 …

Integrating Polyoxometalate into Dy (III)-based Single-molecule Magnets with Pentagonal Bipyramidal Symmetry

H Kong, ZY Ruan, YC Chen, W Deng, PY Liao… - Inorganic …, 2024 - ACS Publications
Polyoxometalates (POMs) with various coordination fashions are versatile ligands for
constructing single-ion magnets (SIMs), but enforcing POM-SIMs with a specific geometry …

Seeking magneto-structural correlations in easily tailored pentagonal bipyramid Dy (III) single-ion magnets

GZ Huang, ZY Ruan, JY Zheng, YC Chen, SG Wu… - Science China …, 2020 - Springer
Controlling molecular magnetic anisotropy via structural engineering is delicate and
fascinating, especially for single-molecule magnets (SMMs). Herein a family of dysprosium …

Macrocycle supported dimetallic lanthanide complexes with slow magnetic relaxation in Dy 2 analogues

FX Shen, K Pramanik, P Brandão, YQ Zhang… - Dalton …, 2020 - pubs.rsc.org
Six dimetallic lanthanide complexes,[Ln2 (L′)(acac) 4](1Dy–3Gd)(Ln= Dy (1Dy), Tb (2Tb)
and Gd (3Gd)) and [Ln2 (L′)(tfac) 4](4Dy–6Gd)(Ln= Dy (4Dy), Tb (5Tb) and Gd …

Synergetic magnetic and luminescence switching via solid state phase transitions of the dysprosium–dianthracene complex

JC Liu, XD Huang, Q Zou, SS Bao, XZ Wang… - Journal of Materials …, 2020 - pubs.rsc.org
Manipulating the synergy between magnetic and optical characteristics in a predictable
manner by an external stimulus is a highly desirable option to develop smart materials for …