Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

We report the use of a P, N-ligand to support a gold complex as a state-of-the-art precatalyst
for the stereoselective hydroamination of internal aryl alkynes with dialkylamines to afford E …

When associated with a noncoordinating bulky counteranion, a cationic Cp* Rh (III)-diamine
catalyst displayed excellent enantioselectivities in asymmetric hydrogenation of cyclic …

The additions of various nucleophiles (XeH) to carbonecarbon (CeC) multiple bonds are of
prime importance in synthetic organic chemistry. These essentially simple reactions allow …

Conspectus Titanium, as the second most abundant transition metal in the earth's crust,
lends itself as a sustainable and inexpensive resource in catalysis. Its nontoxicity and …

Gib mir ein N: Die katalytische Aminierung von α‐Hydroxyamiden mit verschiedenen
Aminen, einschließlich Anilinen, primären und sekundären aliphatischen Aminen und …

Imido complexes of early transition metals are key intermediates in the synthesis of many
nitrogen-containing organic compounds. The metal—nitrogen double bond of the imido …