During the last 20 years the end of the periodic table has been a subject of both
experimental and theoretical interest. Discovery of new elements and their long-lived …

This book provides an introduction to the essentials of relativistic effects in quantum
chemistry, and a reference work that collects all the major developments in this field. It is …

The results of X-ray photoelectron spectroscopy (XPS) studies of the structures of the outer
and inner electron shells of compounds of light actinides (Th, U, Np, Pu, Am, Cm, Bk, Cf) in …

In the last century, three parallel developments have contributed greatly to our
understanding of the elec-tronic structure of the chemicalelements. First, the application of …

The relativistically parameterized extended Hiickel molecular orbital method REX is used to
explore the effects of relativity upon molecularorbital energies and compositions. The …

The electron transfer bands of the triatomic uranyl group are due to a complicated manifold
of excited levels described by relativistic effects in linear symmetry. The lowest of these …

We review recent theoretical and computational advances in the full relativistic four-
component Dirac–Kohn–Sham (DKS) approach and its application to the calculation of the …

While uranyl halide complexes [UO2 (halogen) n] 2–n (n= 1, 2, 4) are ubiquitous, the
tricoordinate species have been relatively unknown until very recently. Here photoelectron …

Bare uranyl tetrafluoride (UO2F42−) and its solvation complexes by one and two water or
acetonitrile molecules have been observed in the gas phase using electrospray ionization …

Dirac molecular orbital calculations on the octahedral rhenium clusters Re 6 S 8 X 6
4−(where X= Cl, Br, I) are reported. The calculated relativistic molecular orbitals indicate that …