In Situ and Emerging Transmission Electron Microscopy for Catalysis Research

HY Chao, K Venkatraman, S Moniri, Y Jiang… - Chemical …, 2023 - ACS Publications
Catalysts are the primary facilitator in many dynamic processes. Therefore, a thorough
understanding of these processes has vast implications for a myriad of energy systems. The …

Single-atom vibrational spectroscopy in the scanning transmission electron microscope

FS Hage, G Radtke, DM Kepaptsoglou, M Lazzeri… - Science, 2020 - science.org
Single-atom impurities and other atomic-scale defects can notably alter the local vibrational
responses of solids and, ultimately, their macroscopic properties. Using high-resolution …

Single-atom vibrational spectroscopy with chemical-bonding sensitivity

M Xu, DL Bao, A Li, M Gao, D Meng, A Li, S Du, G Su… - Nature Materials, 2023 - nature.com
Correlation of lattice vibrational properties with local atomic configurations in materials is
essential for elucidating functionalities that involve phonon transport in solids. Recent …

Progress in ultrahigh energy resolution EELS

OL Krivanek, N Dellby, JA Hachtel, JC Idrobo, MT Hotz… - Ultramicroscopy, 2019 - Elsevier
Electron energy loss spectroscopy (EELS) in the electron microscope has progressed
remarkably in the last five years. Advances in monochromator and spectrometer design …

Phonon spectroscopy at atomic resolution

FS Hage, DM Kepaptsoglou, QM Ramasse, LJ Allen - Physical review letters, 2019 - APS
Advances in source monochromation in transmission electron microscopy have opened up
new possibilities for investigations of condensed matter using the phonon-loss sector of the …

Nanoscale momentum-resolved vibrational spectroscopy

FS Hage, RJ Nicholls, JR Yates, DG McCulloch… - Science …, 2018 - science.org
Vibrational modes affect fundamental physical properties such as the conduction of sound
and heat and can be sensitive to nano-and atomic-scale structure. Probing the momentum …

Basics and applications of ELNES calculations

H Ikeno, T Mizoguchi - Microscopy, 2017 - academic.oup.com
The electron energy loss near edge structures (ELNES) appearing in an electron energy
loss spectrum obtained through transmission electron microscopy (TEM) have the potential …

Vibrational spectroscopy at atomic resolution with electron impact scattering

K Venkatraman, BDA Levin, K March, P Rez… - Nature Physics, 2019 - nature.com
Atomic vibrations control all thermally activated processes in materials, including diffusion,
heat transport, phase transformations and surface chemistry. Recent developments in …

Exploring the capabilities of monochromated electron energy loss spectroscopy in the infrared regime

JA Hachtel, AR Lupini, JC Idrobo - Scientific reports, 2018 - nature.com
Monochromated electron energy loss spectroscopy (EELS) is one of the leading techniques
to study materials properties that correspond to low (< 5 eV) energy losses (ie. band-gaps …

Electron-beam mapping of vibrational modes with nanometer spatial resolution

C Dwyer, T Aoki, P Rez, SLY Chang, TC Lovejoy… - Physical review …, 2016 - APS
We demonstrate that a focused beam of high-energy electrons can be used to map the
vibrational modes of a material with a spatial resolution of the order of one nanometer. Our …