ZnF2‐Riched Inorganic/Organic Hybrid SEI: in situ‐Chemical Construction and Performance‐Improving Mechanism for Aqueous Zinc‐ion Batteries

D Xie, Y Sang, DH Wang, WY Diao… - Angewandte Chemie …, 2023 - Wiley Online Library
Uncontrolled dendrites growth and serious parasitic reactions in aqueous electrolytes,
greatly hinder the practical application of aqueous zinc‐ion battery. On the basis of in situ …

Predicting Degradation Mechanisms in Lithium Bistriflimide “Water‐In‐Salt” Electrolytes For Aqueous Batteries

M Paillot, A Wong, SA Denisov, P Soudan… - …, 2023 - Wiley Online Library
Aqueous solutions are crucial to most domains in biology and chemistry, including in energy
fields such as catalysis and batteries. Water‐in‐salt electrolytes (WISEs), which extend the …

The formation of cerium (III) hydroxide nanoparticles by a radiation mediated increase in local pH

P Abellan, TH Moser, IT Lucas, JW Grate, JE Evans… - RSC …, 2017 - pubs.rsc.org
Here we report radiation-induced formation of Ce (III) nanostructures in an in situ liquid cell
for the transmission electron microscope (TEM). Small (< 5 nm) irregular Ce (OH) 3 …

Are operando measurements of rechargeable batteries always reliable? An example of beam effect with a mg battery

L Blondeau, S Surblé, E Foy, H Khodja… - Analytical …, 2022 - ACS Publications
Operando and in situ techniques are becoming mandatory to study Li-ion, post Li-ion, and
solid-state batteries. They are essential for monitoring the (electro) chemical and dynamic …

[HTML][HTML] Impact of space radiation on lithium-ion batteries: A review from a radiation electrochemistry perspective

G Leita, B Bozzini - Journal of Energy Storage, 2024 - Elsevier
This review paper explores the impact of space radiation on lithium-ion batteries (LIBs), a
critical component in energy storage systems (EESs) for space missions. As national and …

Evaluating the free energies of solvation and electronic structures of lithium‐ion battery electrolytes

M Shakourian‐Fard, G Kamath… - …, 2016 - Wiley Online Library
Adaptive biasing force molecular dynamics simulations and density functional theory
calculations were performed to understand the interaction of Li+ with pure carbonates and …

Operando sum-frequency generation detection of electrolyte redox products at active Si nanoparticle Li-ion battery interfaces

JZ Olson, PK Johansson, DG Castner… - Chemistry of …, 2018 - ACS Publications
For the first time on nanoparticle-based Si electrodes, we monitor electrochemical reduction
products of ethylene carbonate (EC) and fluoroethylene carbonate (FEC) using interface …

Photoelectron Spectroscopic Evidence for Overlapping Redox Reactions for SnO2 Electrodes in Lithium-Ion Batteries

S Böhme, B Philippe, K Edström… - The Journal of Physical …, 2017 - ACS Publications
In-house and synchrotron-based photoelectron spectroscopy (XPS and HAXPES) evidence
is presented for an overlap between the conversion and alloying reaction during the cycling …

Radiolysis of Electrolytes in Batteries: A Quick and Efficient Screening Process for the Selection of Electrolyte‐Additive Formulations

Y Levieux‐Souid, J Martin, P Moreau… - Small …, 2022 - Wiley Online Library
Understanding aging phenomena in batteries is crucial to the design of efficient, safe, and
reliable energy storage devices as a part of the current green energy transition. Among the …

Reaction Mechanisms of the Degradation of Fluoroethylene Carbonate, an Additive of Lithium‐Ion Batteries, Unraveled by Radiation Chemistry

M Puget, V Shcherbakov, S Denisov… - … A European Journal, 2021 - Wiley Online Library
Numerous additives are used in the electrolytes of lithium‐ion batteries, especially for the
formation of an efficient solid electrolyte interphase at the surface of the electrodes …