Homogeneous catalysis with polyhydride complexes
JC Babón, MA Esteruelas, AM López - Chemical Society Reviews, 2022 - pubs.rsc.org
Roles of the hydrogen atoms attached to the metal center of transition metal polyhydride
complexes, LnMHx (x≥ 3), are analyzed for about forty types of organic reactions catalyzed …
complexes, LnMHx (x≥ 3), are analyzed for about forty types of organic reactions catalyzed …
Transition metal polyhydrides: from qualitative ideas to reliable computational studies
A. Hydride Is the Smallest Ligand and the Only One To Make a Pure Single Bond to a Metal
Hydride is the ligand with the smallest number of valence electrons and thus an ideal choice …
Hydride is the ligand with the smallest number of valence electrons and thus an ideal choice …
Open-shell organometallics as a bridge between Werner-type and low-valent organometallic complexes. The effect of the spin state on the stability, reactivity, and …
R Poli - Chemical reviews, 1996 - ACS Publications
can be attributed to the discovery and development of the metallocenes by Wilkinson and
Fischer, 1 the field has been and is still dominated by compounds that follow the so-called …
Fischer, 1 the field has been and is still dominated by compounds that follow the so-called …
An acidity scale for phosphorus-containing compounds including metal hydrides and dihydrogen complexes in THF: toward the unification of acidity scales
K Abdur-Rashid, TP Fong, B Greaves… - Journal of the …, 2000 - ACS Publications
More than 70 equilibrium constants K between acids and bases, mainly phosphine
derivatives, have been measured in tetrahydrofuran (THF) at 20° C by 1H and/or 31P NMR …
derivatives, have been measured in tetrahydrofuran (THF) at 20° C by 1H and/or 31P NMR …
[图书][B] Chemistry of precious metals
SA Cotton - 2012 - books.google.com
Some 20 years ago, I was privileged to share in writing a book on the descriptive chemistry
of the 4d, 5d, 4f and 5f metals that included these eight elements within its compass (SA …
of the 4d, 5d, 4f and 5f metals that included these eight elements within its compass (SA …
Polyhydrides of platinum group metals: Nonclassical interactions and σ-bond activation reactions
MA Esteruelas, AM Lopez, M Olivan - Chemical Reviews, 2016 - ACS Publications
The preparation, structure, dynamic behavior in solution, and reactivity of polyhydride
complexes of platinum group metals, described during the last three decades, are …
complexes of platinum group metals, described during the last three decades, are …
Direct access to pop-type osmium (II) and osmium (IV) complexes: Osmium a promising alternative to ruthenium for the synthesis of imines from alcohols and amines
MA Esteruelas, N Honczek, M Oliván, E Onate… - …, 2011 - ACS Publications
An easy and direct access to POP-type osmium (II) and osmium (IV) complexes, including
OsH4 {dbf (P i Pr2) 2}(dbf (P i Pr2) 2= 4, 6-bis (diisopropylphosphine) dibenzofuran), is …
OsH4 {dbf (P i Pr2) 2}(dbf (P i Pr2) 2= 4, 6-bis (diisopropylphosphine) dibenzofuran), is …
Alternative conceptual approach to the design of bifunctional catalysts: an osmium germylene system for the dehydrogenation of formic acid
ML Buil, JA Cabeza, MA Esteruelas… - Inorganic …, 2021 - ACS Publications
The reaction of the hexahydride OsH6 (PiPr3) 2 with a P, Ge, P-germylene-diphosphine
affords an osmium tetrahydride derivative bearing a Ge, P-chelate, which arises from the …
affords an osmium tetrahydride derivative bearing a Ge, P-chelate, which arises from the …
Osmium–carbon double bonds: Formation and reactions
MA Esteruelas, AM López, M Oliván - Coordination chemistry reviews, 2007 - Elsevier
The present review reports on the chemistry of the osmium–carbon double bond, including
alkylidene or carbene, vinylidene, and allenylidene derivatives. Within the first type of …
alkylidene or carbene, vinylidene, and allenylidene derivatives. Within the first type of …
CCC–pincer–NHC osmium complexes: New types of blue-green emissive neutral compounds for organic light-emitting devices (OLEDs)
RG Alabau, B Eguillor, J Esler, MA Esteruelas… - …, 2014 - ACS Publications
Novel homoleptic and heteroleptic NHC carbene containing bis (tridentate) osmium (II)
complexes have been designed, synthesized, and characterized, and their photophysical …
complexes have been designed, synthesized, and characterized, and their photophysical …