Molecular spin qudits for quantum algorithms

E Moreno-Pineda, C Godfrin, F Balestro… - Chemical Society …, 2018 - pubs.rsc.org
Presently, one of the most ambitious technological goals is the development of devices
working under the laws of quantum mechanics. One prominent target is the quantum …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

[PDF][PDF] The origin of nonmagnetic Kramers doublets in the ground state of dysprosium triangles: evidence for a toroidal magnetic moment

L Chibotaru, L Ungur, A Soncini - … Chemie-International Edition, 2008 - lirias.kuleuven.be
Triangular donuts: High-level ab initio calculations reveal a toroidal arrangement of local
magnetizations at dysprosium sites in the ground state of triangular dysprosium complexes …

Magnetic anisotropy in the excited states of low symmetry lanthanide complexes

L Ungur, LF Chibotaru - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
Ab initio investigation of multiplet spectrum of lanthanides in archetypal coordination
geometries shows an unexpected regular structure consisting of (i) mirror symmetry of …

Slow magnetic relaxation in a family of trigonal pyramidal iron (II) pyrrolide complexes

WH Harman, TD Harris, DE Freedman… - Journal of the …, 2010 - ACS Publications
We present a family of trigonal pyramidal iron (II) complexes supported by tris (pyrrolyl-α-
methyl) amine ligands of the general formula [M (solv) n][(tpaR) Fe](M= Na, R= tert-butyl (1) …

A mononuclear transition metal single-molecule magnet in a nuclear spin-free ligand environment

MS Fataftah, JM Zadrozny, DM Rogers… - Inorganic …, 2014 - ACS Publications
The high-spin pseudotetrahedral complex [Co (C3S5) 2] 2–exhibits slow magnetic
relaxation in the absence of an applied dc magnetic field, one of a small number of …

Field‐induced hysteresis and quantum tunneling of the magnetization in a mononuclear manganese (III) complex

J Vallejo, A Pascual‐Álvarez, J Cano… - Angewandte …, 2013 - Wiley Online Library
High-nuclearity complexes of transition-metal ions have been of special interest during the
last two decades owing to the possibility of observing slow magnetic relaxation effects at the …

The quantum magnetism of individual manganese-12-acetate molecular magnets anchored at surfaces

S Kahle, Z Deng, N Malinowski, C Tonnoir… - Nano …, 2012 - ACS Publications
The high intrinsic spin and long spin relaxation time of manganese-12-acetate (Mn12)
makes it an archetypical single molecular magnet. While these characteristics have been …

Spin dynamics in the negatively charged terbium (III) bis-phthalocyaninato complex

F Branzoli, P Carretta, M Filibian… - Journal of the …, 2009 - ACS Publications
The experimental and theoretical study of the electron spin dynamics in the anionic form of a
single-ion molecule magnet (SIMM), the bis-phthalocyaninato terbium (III) molecule [Pc …

Systematic Study of a Family of Butterfly-Like {M2Ln2} Molecular Magnets (M = MgII, MnIII, CoII, NiII, and CuII; Ln = YIII, GdIII, TbIII, DyIII, HoIII, and ErIII)

E Moreno Pineda, NF Chilton, F Tuna… - Inorganic …, 2015 - ACS Publications
A family of 3d–4f [MII2LnIII2 (μ3-OH) 2 (O2C t Bu) 10] 2–“butterflies”(where MII= Mg, Co, Ni,
and Cu; LnIII= Y, Gd, Tb, Dy, Ho, and Er) and [MnIII2LnIII2 (μ3-O) 2 (O2C t Bu) 10] 2 …