Oxygen loss in layered oxide cathodes for Li-ion batteries: mechanisms, effects, and mitigation

H Zhang, H Liu, LFJ Piper, MS Whittingham… - Chemical …, 2022 - ACS Publications
Layered lithium transition metal oxides derived from LiMO2 (M= Co, Ni, Mn, etc.) have been
widely adopted as the cathodes of Li-ion batteries for portable electronics, electric vehicles …

Cobalt‐free cathode materials: families and their prospects

H Zhao, WYA Lam, L Sheng, L Wang… - Advanced Energy …, 2022 - Wiley Online Library
With the rapid growth of global electro‐mobility, the demand for cobalt is rapidly increasing
because it is currently an indispensable component of the cathode materials in lithium‐ion …

Relieving stress concentration through anion–cation codoping toward highly stable nickel-rich cathode

Y Zhou, H Zhang, Y Wang, T Wan, P Guan, X Zhou… - ACS …, 2023 - ACS Publications
Nickel-rich LiNi0. 8Co0. 15Al0. 015O2 (NCA) with excellent energy density is considered
one of the most promising cathodes for lithium-ion batteries. Nevertheless, the stress …

In situ inorganic conductive network formation in high-voltage single-crystal Ni-rich cathodes

X Fan, X Ou, W Zhao, Y Liu, B Zhang, J Zhang… - Nature …, 2021 - nature.com
High nickel content in LiNixCoyMnzO2 (NCM, x≥ 0.8, x+ y+ z= 1) layered cathode material
allows high specific energy density in lithium-ion batteries (LIBs). However, Ni-rich NCM …

Surface enrichment and diffusion enabling gradient-doping and coating of Ni-rich cathode toward Li-ion batteries

H Yu, Y Cao, L Chen, Y Hu, X Duan, S Dai, C Li… - Nature …, 2021 - nature.com
Critical barriers to layered Ni-rich cathode commercialisation include their rapid capacity
fading and thermal runaway from crystal disintegration and their interfacial instability …

A perspective on single-crystal layered oxide cathodes for lithium-ion batteries

J Langdon, A Manthiram - Energy Storage Materials, 2021 - Elsevier
As the demand for lithium-ion batteries grows exponentially to feed the nascent electric-
vehicle and grid-storage markets, the need for higher energy density and longer cycle life …

Strain engineering of Ni‐rich cathode enables exceptional cyclability in pouch‐type full cells

H Zhu, Z Wang, L Chen, Y Hu, H Jiang… - Advanced …, 2023 - Wiley Online Library
Ni‐rich layered oxides are at the forefront of the development of high‐energy Li‐ion
batteries, yet the extensive applications are retarded by the deteriorative capacity and …

Can cobalt be eliminated from lithium-ion batteries?

S Lee, A Manthiram - ACS Energy Letters, 2022 - ACS Publications
Following the discovery of LiCoO2 (LCO) as a cathode in the 1980s, layered oxides have
enabled lithium-ion batteries (LIBs) to power portable electronic devices that sparked the …

Challenges of Stable Ion Pathways in Cathode Electrode for All‐Solid‐State Lithium Batteries: A Review

S Huo, L Sheng, W Xue, L Wang, H Xu… - Advanced Energy …, 2023 - Wiley Online Library
For energy storage devices, high energy density, high power density, cycle stability, and
safety are the development goals. Solid‐state lithium metal batteries, with both safety and …

Crack-free single-crystalline Ni-rich layered NCM cathode enable superior cycling performance of lithium-ion batteries

X Fan, G Hu, B Zhang, X Ou, J Zhang, W Zhao, H Jia… - Nano Energy, 2020 - Elsevier
Ni-rich layered oxides are extensively employed as a promising cathode material in lithium
ion batteries (LIBs) due to their high energy density and reasonable cost. However, the …