Spin crossover in iron (III) complexes
Spin crossover compounds are a diverse class of switchable materials with applications
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
Understanding of cooperative effects in molecule-based spin transition materials
Y Fang, YS Meng, H Oshio, T Liu - Coordination Chemistry Reviews, 2024 - Elsevier
Spin transition (ST) materials, exhibiting spin state conversions by external stimuli, have
been studied for over a half-century and have been continuing research interests owing to …
been studied for over a half-century and have been continuing research interests owing to …
Solvent modified spin crossover in an iron (III) complex: phase changes and an exceptionally wide hysteresis
Solvent effects in a series of Fe (III) spin crossover (SCO) complexes [Fe (qsal-I) 2] OTf· sol
(sol= MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is …
(sol= MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is …
Stimuli-responsive magnetic materials: impact of spin and electronic modulation
Addressing molecular bistability as a function of external stimuli, especially in spin-crossover
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …
Structural and theoretical insights into solvent effects in an iron (III) SCO complex
Alcohol effects in a series of iron (III) spin crossover complexes [Fe (qsal-Cl) 2] NO3· ROH
(R= Me 1, Et 2, 1-Pr 3) are explored. Despite the solvents differing from each other by only …
(R= Me 1, Et 2, 1-Pr 3) are explored. Despite the solvents differing from each other by only …
Thermal spin crossover in Fe (II) and Fe (III). Accurate spin state energetics at the solid state
The thermal spin crossover (SCO) phenomenon refers to an entropy-driven spin transition in
some materials based on d6–d9 transition metal complexes. While its molecular origin is …
some materials based on d6–d9 transition metal complexes. While its molecular origin is …
Spin Crossover in Iron(III) Quinolylsalicylaldiminates: The Curious Case of [Fe(qsal-F)2](Anion)
A family of iron (III) spin crossover complexes with different counteranions,[Fe (qsal-F) 2] A
(qsal-F= 4-fluoro-2-[(8-quinolylimino) methyl] phenolate; A= PF6–1, OTf–2, NO3–3, ClO4–4 …
(qsal-F= 4-fluoro-2-[(8-quinolylimino) methyl] phenolate; A= PF6–1, OTf–2, NO3–3, ClO4–4 …
Halogen Substitution Effects on N2O Schiff Base Ligands in Unprecedented Abrupt FeII Spin Crossover Complexes
A family of halogen‐substituted Schiff base iron (II) complexes,[FeII (qsal‐X) 2],(qsal‐X= 5‐X‐
N‐(8‐quinolyl) salicylaldimines)) in which X= F (1), Cl (2), Br (3) or I (4) has been …
N‐(8‐quinolyl) salicylaldimines)) in which X= F (1), Cl (2), Br (3) or I (4) has been …
Synergistic Spin Transition between Spin Crossover and Spin‐Peierls‐like Singlet Formation in the Halogen‐Bonded Molecular Hybrid System: [Fe(Iqsal)2][Ni(dmit)2]⋅CH3CN …
K Fukuroi, K Takahashi, T Mochida… - Angewandte …, 2014 - Wiley Online Library
To introduce halogen‐bond interactions between a cation and an anion, a novel FeIII
complex from iodine‐substituted ligands involving a paramagnetic nickel dithiolene anion …
complex from iodine‐substituted ligands involving a paramagnetic nickel dithiolene anion …
Synthesis, characterization and anticancer activity of Fe(II) and Fe(III) complexes containing N-(8-quinolyl)salicylaldimine Schiff base ligands
S Wongsuwan, J Chatwichien, B Pinchaipat… - JBIC Journal of …, 2021 - Springer
A series of Fe (II) complexes (1–4) and Fe (III) complexes (5–8) from Fe (II)/(III) chloride and
N-(8-quinolyl)-X-salicylaldimine Schiff base ligands (Hqsal-X 2/X: X= Br, Cl) were …
N-(8-quinolyl)-X-salicylaldimine Schiff base ligands (Hqsal-X 2/X: X= Br, Cl) were …