Laboratory studies of organic peroxy radical chemistry: an overview with emphasis on recent issues of atmospheric significance

JJ Orlando, GS Tyndall - Chemical Society Reviews, 2012 - pubs.rsc.org
Organic peroxy radicals (often abbreviated RO2) play a central role in the chemistry of the
Earth's lower atmosphere. Formed in the atmospheric oxidation of essentially every organic …

Atmospheric chemistry of iodine

A Saiz-Lopez, JMC Plane, AR Baker… - Chemical …, 2012 - ACS Publications
The atmospheric chemistry of iodine is important in diverse ways. First, it provides the route
for iodine, which is an essential dietary element for mammals, to be transported from its …

Iodine chemistry in the troposphere and its effect on ozone

A Saiz-Lopez, RP Fernandez, C Ordóñez… - Atmospheric …, 2014 - acp.copernicus.org
Despite the potential influence of iodine chemistry on the oxidizing capacity of the
troposphere, reactive iodine distributions and their impact on tropospheric ozone remain …

Rate constant of the reaction between CH3O2 and OH radicals

A Bossolasco, EP Faragó, C Schoemaecker… - Chemical Physics …, 2014 - Elsevier
The rate constant of the reaction (R1) OH+ CH 3 O 2→ products has been measured at 294
K by simultaneous coupling of Laser Induced Fluorescence (LIF) and cw-Cavity Ring Down …

Coupling of HOx, NOx and halogen chemistry in the antarctic boundary layer

WJ Bloss, M Camredon, JD Lee… - Atmospheric …, 2010 - acp.copernicus.org
A modelling study of radical chemistry in the coastal Antarctic boundary layer, based upon
observations performed in the course of the CHABLIS (Chemistry of the Antarctic Boundary …

Laser induced fluorescence studies of iodine oxide chemistry Part II. The reactions of IO with CH 3 O 2, CF 3 O 2 and O 3

TJ Dillon, ME Tucceri, JN Crowley - Physical Chemistry Chemical …, 2006 - pubs.rsc.org
The technique of pulsed laser photolysis was coupled to laser induced fluorescence
detection of iodine oxide (IO) to measure rate coefficients, k for the reactions IO+ CH3O2→ …

Uncertainties in gas-phase atmospheric iodine chemistry

R Sommariva, WJ Bloss, R Von Glasow - Atmospheric Environment, 2012 - Elsevier
We present a comprehensive chemical mechanism for gas-phase iodine, to be used for
modelling tropospheric chemistry. The mechanism has been compiled from evaluated data …

Measurement of IO radical concentrations in the marine boundary layer using a cavity ring-down spectrometer

R Wada, JM Beames, AJ Orr-Ewing - Journal of Atmospheric Chemistry, 2007 - Springer
An open-path cavity ring-down spectroscopy (CRDS) instrument for measurement of
atmospheric iodine monoxide (IO) radicals has been tested in the laboratory and …

Box modelling of gas-phase atmospheric iodine chemical reactivity in case of a nuclear accident

C Fortin, V Fèvre-Nollet, F Cousin, P Lebègue… - Atmospheric …, 2019 - Elsevier
A new atmospheric iodine gas-phase mechanism containing 248 reactions combined to the
RACM air quality mechanism was implemented into a 0D box model in order to evaluate the …

LIF studies of iodine oxide chemistry Part 3. Reactions IO+ NO 3→ OIO+ NO 2, I+ NO 3→ IO+ NO 2, and CH 2 I+ O 2→(products): implications for the chemistry of the …

TJ Dillon, ME Tucceri, R Sander… - Physical Chemistry …, 2008 - pubs.rsc.org
The technique of pulsed laser photolysis coupled to LIF detection of IO was used to study
reactions:(R1a) IO+ NO3→ OIO+ NO2;(R2) I+ NO3→(products);(R3) CH2I+ O2→(products); …