Crystallization by particle attachment in synthetic, biogenic, and geologic environments

JJ De Yoreo, PUPA Gilbert, NAJM Sommerdijk… - Science, 2015 - science.org
BACKGROUND Numerous lines of evidence challenge the traditional interpretations of how
crystals nucleate and grow in synthetic and natural systems. In contrast to the monomer-by …

Biomineralization: Integrating mechanism and evolutionary history

PUPA Gilbert, KD Bergmann, N Boekelheide… - Science …, 2022 - science.org
Calcium carbonate (CaCO3) biomineralizing organisms have played major roles in the
history of life and the global carbon cycle during the past 541 Ma. Both marine diversification …

Carbonation behavior of calcium silicate hydrate (CSH): Its potential for CO2 capture

X Liu, P Feng, Y Cai, X Yu, C Yu, Q Ran - Chemical Engineering Journal, 2022 - Elsevier
Calcium silicate hydrate (CSH), as the main component of cementitious materials, is
susceptible to carbonation presenting a potential to capture CO 2. Although some …

Preparation aragonite whisker-rich materials by wet carbonation of cement: Towards yielding micro-fiber reinforced cement and sequestrating CO2

P Shen, J Lu, Y Zhang, Y Jiang, S Zhang… - Cement and Concrete …, 2022 - Elsevier
In this study, an innovative wet carbonation process was developed to prepare aragonite
whisker-rich materials (AWM) from cement and simulated flue gas, which subsequently …

Production of aragonite whiskers by carbonation of fine recycled concrete wastes: an alternative pathway for efficient CO2 sequestration

P Shen, Y Jiang, Y Zhang, S Liu, D Xuan, J Lu… - … and Sustainable Energy …, 2023 - Elsevier
In this study, a wet carbonation method targeting high carbonation rate was developed to
prepare aragonite whisker using fine recycled concrete waste (FRCW), aiming to effectively …

Pre-nucleation clusters as solute precursors in crystallisation

D Gebauer, M Kellermeier, JD Gale… - Chemical Society …, 2014 - pubs.rsc.org
Crystallisation is at the heart of various scientific disciplines, but still the understanding of the
molecular mechanisms underlying phase separation and the formation of the first solid …

Effect of relative humidity on the carbonation rate of portlandite, calcium silicate hydrates and ettringite

S Steiner, B Lothenbach, T Proske… - Cement and Concrete …, 2020 - Elsevier
The carbonation of portlandite, calcium silicate hydrate (CSH), and ettringite was
investigated at 57% RH and 91% RH using X-ray diffraction, thermogravimetric analysis …

Amorphous calcium carbonate particles form coral skeletons

T Mass, AJ Giuffre, CY Sun, CA Stifler… - Proceedings of the …, 2017 - National Acad Sciences
Do corals form their skeletons by precipitation from solution or by attachment of amorphous
precursor particles as observed in other minerals and biominerals? The classical model …

Biomineralization: from material tactics to biological strategy

S Yao, B Jin, Z Liu, C Shao, R Zhao, X Wang… - Advanced …, 2017 - Wiley Online Library
Biomineralization is an important tactic by which biological organisms produce hierarchically
structured minerals with marvellous functions. Biomineralization studies typically focus on …

In situ TEM imaging of CaCO3 nucleation reveals coexistence of direct and indirect pathways

MH Nielsen, S Aloni, JJ De Yoreo - Science, 2014 - science.org
Mechanisms of nucleation from electrolyte solutions have been debated for more than a
century. Recent discoveries of amorphous precursors and evidence for cluster aggregation …