New methods for preparation of tailor-made fluorine-containing compounds are in extremely
high demand in nearly every sector of chemical industry. The asymmetric construction of …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

The high utility of halogenated organic compounds has prompted the development of a vast
number of transformations which install the carbon–halogen motif. Traditional routes to …

Taking into account the vast arrays of fluorinated motifs known, 11 this review will be limited
to the monofluorination of organic compounds, ie, synthetic methods allowing the …

Oxazoline-containing ligands have been widely employed in numerous asymmetric catalytic
reactions. Pyridine-oxazoline-type ligands, a class of hybrid ligands, were designed earlier …

Reported herein is a new iron‐catalyzed diastereoselective olefin diazidation reaction which
occurs at room temperature (1–5 mol% of catalysts and dr values of up to> 20: 1). This …

Rapid and efficient access to structurally diverse β-fluoroalkylamines is in high demand, with
their wide presence and great importance in medicinal chemistry and drug development …

Recent advances in nitrene chemistry from acyclic precursors are reviewed in this paper.
Early developments in nitrene chemistry predominantly focused on exploiting new nitrene …

An iron-catalyzed diastereoselective intermolecular olefin amino-oxygenation reaction is
reported, which proceeds via an iron-nitrenoid generated by the N–O bond cleavage of a …

Alkenes are versatile building blocks in modern organic synthesis. In the difunctionalization
reactions of alkenes, two functional groups can be simultaneously introduced into the π …