USc2C2 and USc2NC Clusters with U–C Triple Bond Character Stabilized Inside Fullerene Cages
H Jiang, X Yu, M Guo, YR Yao, Q Meng… - Journal of the …, 2023 - ACS Publications
The chemistry of f-block metal–carbon multiple bonds is underdeveloped compared to well-
established carbene complexes of the d-block transition metals. Herein, we report two new …
established carbene complexes of the d-block transition metals. Herein, we report two new …
Metal–ligand multiple bonding in uranium: structure and reactivity
TW Hayton - Dalton Transactions, 2010 - pubs.rsc.org
There is a growing interest in uranium coordination chemistry, particularly as it relates to
metal–ligand multiple bonding, and in the last decade significant progress has been made …
metal–ligand multiple bonding, and in the last decade significant progress has been made …
Purification of uranium‐based endohedral metallofullerenes (EMFs) by selective supramolecular encapsulation and release
C Fuertes‐Espinosa, A Gómez‐Torres… - Angewandte …, 2018 - Wiley Online Library
Abstract Supramolecular nanocapsule 1⋅(BArF) 8 is able to sequentially and selectively
entrap recently discovered U2@ C80 and unprecedented Sc2CU@ C80, simply by soaking …
entrap recently discovered U2@ C80 and unprecedented Sc2CU@ C80, simply by soaking …
Matrix Preparation and Spectroscopic and Theoretical Investigations of Simple Methylidene and Methylidyne Complexes of Group 4− 6 Transition Metals
L Andrews, HG Cho - Organometallics, 2006 - ACS Publications
A new generation of simple methylidene complexes has been prepared by reactions of
excited group 4− 6 transition metal atoms with methyl halides and methane in solid argon …
excited group 4− 6 transition metal atoms with methyl halides and methane in solid argon …
A diuranium carbide cluster stabilized inside a C80 fullerene cage
Unsupported non-bridged uranium–carbon double bonds have long been sought after in
actinide chemistry as fundamental synthetic targets in the study of actinide-ligand multiple …
actinide chemistry as fundamental synthetic targets in the study of actinide-ligand multiple …
Synthesis and electronic structure analysis of the actinide allenylidenes,[{(NR 2) 3} An (CCCPh 2)]−(An= U, Th; R= SiMe 3)
GT Kent, X Yu, G Wu, J Autschbach, TW Hayton - Chemical Science, 2021 - pubs.rsc.org
The reaction of [AnCl (NR2) 3](An= U, Th, R= SiMe3) with in situ generated lithium-3, 3-
diphenylcyclopropene results in the formation of [{(NR2) 3} An (CHCCPh2)](An= U, 1; Th, 2) …
diphenylcyclopropene results in the formation of [{(NR2) 3} An (CHCCPh2)](An= U, 1; Th, 2) …
Double dative bond between divalent carbon (0) and uranium
Dative bonds between p-and d-block atoms are common but species containing a double
dative bond, which donate two-electron pairs to the same acceptor, are far less common …
dative bond, which donate two-electron pairs to the same acceptor, are far less common …
Uranium (III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
AJ Wooles, DP Mills, F Tuna, EJL McInnes… - Nature …, 2018 - nature.com
Despite the fact that non-aqueous uranium chemistry is over 60 years old, most polarised-
covalent uranium-element multiple bonds involve formal uranium oxidation states IV, V, and …
covalent uranium-element multiple bonds involve formal uranium oxidation states IV, V, and …
Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium
DE Smiles, G Wu, P Hrobárik, TW Hayton - Organometallics, 2017 - ACS Publications
Reaction of the Th (IV) metallacycle [Th (C H2SiMe2 N SiMe3)(NR2) 2](1; R= SiMe3), with
Ph3P CH2 affords the Th (IV) carbene [Th (CHPPh3)(NR2) 3](2) in good yield. In solution …
Ph3P CH2 affords the Th (IV) carbene [Th (CHPPh3)(NR2) 3](2) in good yield. In solution …
Nature of the Arsonium‐Ylide Ph3As=CH2 and a Uranium(IV) Arsonium–Carbene Complex
JA Seed, HR Sharpe, HJ Futcher… - Angewandte Chemie …, 2020 - Wiley Online Library
Abstract Treatment of [Ph3EMe][I] with [Na {N (SiMe3) 2}] affords the ylides [Ph3E= CH2](E=
As, 1As; P, 1P). For 1As this overcomes prior difficulties in the synthesis of this classical …
As, 1As; P, 1P). For 1As this overcomes prior difficulties in the synthesis of this classical …