Catalytic Enantioselective Hydrogen Atom Abstraction Enables the Asymmetric Oxidation of Meso Diols

NYS Lam, J Dhankhar… - Journal of the …, 2024 - ACS Publications
Desymmetrization of meso diols is an important strategy for the synthesis of chiral oxygen-
containing building blocks. Oxidative desymmetrization is an important subclass, but existing …

Total Synthesis and Structural Revision of the 6, 11-Epoxyisodaucane Natural Sesquiterpene Using an Anionic 8π Electrocyclic Reaction

R Kato, H Saito, K Ikeuchi, T Suzuki, K Tanino - Organic Letters, 2022 - ACS Publications
A new synthetic strategy that forms a seven-membered carbocycle using an anionic 8π
electrocyclic reaction facilitated the first total synthesis of the 6, 11-epoxyisodaucane natural …

Mechanistic Details of the Sharpless Epoxidation of Allylic Alcohols—A Combined URVA and Local Mode Study

M Freindorf, E Kraka - Catalysts, 2022 - mdpi.com
In this work, we investigated the catalytic effects of a Sharpless dimeric titanium (IV)–tartrate–
diester catalyst on the epoxidation of allylalcohol with methyl–hydroperoxide considering …

[PDF][PDF] Mechanistic Details of the Sharpless Epoxidation of Allylic Alcohols—A Combined URVA and Local Mode Study. Catalysts 2022, 12, 789

M Freindorf, E Kraka - 2022 - academia.edu
In this work, we investigated the catalytic effects of a Sharpless dimeric titanium (IV)–tartrate–
diester catalyst on the epoxidation of allylalcohol with methyl–hydroperoxide considering …

[引用][C] Diastereoselective Aldol Reactions

SCD Kennington, AM Costa, P Romea, F Urpí - 2022 - Elsevier