C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Surface organometallic chemistry is an area of heterogeneous catalysis which has recently
emerged as a result of a comparative analysis of homogeneous and heterogeneous …

Mechanistic assessments based on kinetic and isotopic methods combined with density
functional theory are used to probe the diverse pathways by which C–H bonds in CH4 react …

This study reports the highly selective (more than 95%) dehydrogenation of propane to
propylene as well as the reverse hydrogenation reaction by silica-supported single-site Zn …

CH3, CH2CH3; Ln= Nd, R= CH2CH3) and Cp'2LaŅCH (CH3) CH2CR2CH2 (HNCH (CH3)
CH2CR2CH2)(R= H, CH3) were synthesized to model species in the catalytic cycle …

We have foundthat the bisamides Cp2Zr (NHR) 2 (1) catalyzethe hydroamination of alkynes
and aliene and have investigated the scope and mechanism of this process. Examining both …

A series of studies have been conducted by experimental and theoretical methods on the
synthesis, structures, and reactions of Cp* Rh boryl complexes that are likely intermediates …

Kinetic and isotopic data and density functional theory treatments provide evidence for the
elementary steps and the active site requirements involved in the four distinct kinetic …

This paper outlines the generation of the transient monomeric imido complexes Cp2Zr= NR
(la-e), their successful trapping with unsaturated organic molecules and dative ligands, and …