1. INTRODUCTION Bulk gold, being the most stable among all metals, was for many years
considered as an inert catalyst. However, gold particles with size on the scale of nanometers …

Abstract Chiral Si-, P-, and S-containing organic compounds with central, planar, and axial
chiralities have found a plethora of applications in various fields of chemistry. Despite …

The amino imidazolin-2-imine ligand [HAmIm, 1, 2-(DippNH)–C6H4–N═ C (N i PrCMe) 2] is
employed in the synthesis of the paramagnetic cobalt (I) arene complex Co (AmIm)(η 6 …

[Cp* RuCl] 4 (1) has previously been shown to be the precatalyst of choice for
stereochemically unorthodox trans-hydrometalations of internal alkynes. Experimental and …

The first highly efficient ligand-controlled regio-and stereodivergent intermolecular
hydrosilylations of internal alkynes have been disclosed. Cationic ruthenium complexes …

The current work describes the marked rate of acceleration caused by phosphine ligands on
the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C (sp3)–H …

We report a polysiloxane based single-ion conducting polymer electrolyte (SIPE)
synthesized via a hydrosilylation technique. Styrenesulfonyl (phenylsulfonyl) imide groups …

During the last ten years, base metals have become very attractive to the organometallic and
catalytic community on activation of CH bonds for their catalytic functionalization. In contrast …

Selectivity control in the addition reactions of internal alkynes that bear two similar
substituents presents a big challenge in modern organic synthesis. Herein we report that β …

Cationic rhodium (I) complexes containing picolyl-NHC (NHC= N-heterocyclic carbene)
ligands that differ in the substitution at the 6-position of the pyridine donor serve as efficient …