Cononsolvency of thermoresponsive polymers: where we are now and where we are going

S Bharadwaj, BJ Niebuur, K Nothdurft, W Richtering… - Soft Matter, 2022 - pubs.rsc.org
Cononsolvency is an intriguing phenomenon where a polymer collapses in a mixture of
good solvents. This cosolvent-induced modulation of the polymer solubility has been …

[HTML][HTML] Switching (bio-) adhesion and friction in liquid by stimulus responsive polymer coatings

Y Yu, MB Pérez, C Cao, S de Beer - European Polymer Journal, 2021 - Elsevier
Controlling (bio-) adhesion and friction is essential in many bio-medical and industrial
applications. Such control can be achieved using stimulus responsive polymers. Coatings …

Solvation Behavior of Elastin-like Polypeptides in Divalent Metal Salt Solutions

Y Zhao, S Bharadwaj, RL Myers, HI Okur… - The Journal of …, 2023 - ACS Publications
The effects of CaCl2 and MgCl2 on the cloud point temperature of two different elastin-like
polypeptides (ELPs) were studied using a combination of cloud point measurements …

Smart polymers for soft materials: from solution processing to organic solids

D Mukherji, K Kremer - Polymers, 2023 - mdpi.com
Polymeric materials are ubiquitous in our everyday life, where they find a broad range of
uses—spanning across common household items to advanced materials for modern …

Polymer cyclization for the emergence of hierarchical nanostructures

C Chen, MK Singh, K Wunderlich, S Harvey… - Nature …, 2021 - nature.com
The creation of synthetic polymer nanoobjects with well-defined hierarchical structures is
important for a wide range of applications such as nanomaterial synthesis, catalysis, and …

The construction of elastin-like polypeptides and their applications in drug delivery system and tissue repair

Y Guo, S Liu, D Jing, N Liu, X Luo - Journal of Nanobiotechnology, 2023 - Springer
Elastin-like polypeptides (ELPs) are thermally responsive biopolymers derived from natural
elastin. These peptides have a low critical solution temperature phase behavior and can be …

Metal-organic frameworks' tricks in asymmetric catalysis

J Guo, Y Lian, F Li, Y Duan, X Xue, C Long, Y Zhang… - Chem Catalysis, 2022 - cell.com
Asymmetric catalysis plays an irreplaceable role in the fields of pharmaceuticals,
biomaterials, pesticides, and chiral optics. Due to the lessons from the specific catalysis …

[HTML][HTML] An interplay of excluded-volume and polymer–(co) solvent attractive interactions regulates polymer collapse in mixed solvents

S Bharadwaj, D Nayar, C Dalgicdir… - The Journal of …, 2021 - pubs.aip.org
Cosolvent effects on the coil–globule transitions in aqueous polymer solutions are not well
understood, especially in the case of amphiphilic cosolvents that preferentially adsorb on the …

Stabilizing α-Helicity of a Polypeptide in Aqueous Urea: Dipole Orientation or Hydrogen Bonding?

LA Baptista, Y Zhao, K Kremer, D Mukherji… - ACS Macro …, 2023 - ACS Publications
We propose a mechanism for α-helix folding of polyalanine in aqueous urea that reconciles
experimental and simulation studies. Over 15 μs long, all-atom simulations reveal that, upon …

Thermal compaction of disordered and elastin-like polypeptides: a temperature-dependent, sequence-specific coarse-grained simulation model

U Baul, M Bley, J Dzubiella - Biomacromolecules, 2020 - ACS Publications
Elastin-like polypeptides (ELPs) undergo a sharp solubility transition from low-temperature
solvated phases to coacervates at elevated temperatures, driven by the increased strength …