Visible-to-NIR-light activated release: from small molecules to nanomaterials

R Weinstain, T Slanina, D Kand, P Klan - Chemical reviews, 2020 - ACS Publications
Photoactivatable (alternatively, photoremovable, photoreleasable, or photocleavable)
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …

Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Copolymerization involving sulfur-containing monomers

TJ Yue, WM Ren, XB Lu - Chemical Reviews, 2023 - ACS Publications
Incorporating sulfur (S) atoms into polymer main chains endows these materials with many
attractive features, including a high refractive index, mechanical properties, electrochemical …

Covalently Crosslinked hydrogels via step‐growth reactions: crosslinking chemistries, polymers, and clinical impact

Y Gao, K Peng, S Mitragotri - Advanced Materials, 2021 - Wiley Online Library
Hydrogels are an important class of biomaterials with the unique property of high‐water
content in a crosslinked polymer network. In particular, chemically crosslinked hydrogels …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Cu (0)-mediated living radical polymerization: a versatile tool for materials synthesis

A Anastasaki, V Nikolaou, G Nurumbetov… - Chemical …, 2016 - ACS Publications
During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis

CE Hoyle, AB Lowe, CN Bowman - Chemical Society Reviews, 2010 - pubs.rsc.org
The merits of thiol-click chemistry and its potential for making new forays into chemical
synthesis and materials applications are described. Since thiols react to high yields under …

Thiol-ene “click” reactions and recent applications in polymer and materials synthesis

AB Lowe - Polymer Chemistry, 2010 - pubs.rsc.org
This review highlights examples of recent applications of both the radical-mediated and
base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis. Initial …

Transition metal-catalyzed living radical polymerization: toward perfection in catalysis and precision polymer synthesis

M Ouchi, T Terashima, M Sawamoto - Chemical Reviews, 2009 - ACS Publications
Precision control of radical polymerization, or living radical polymerization, has been among
the most important and long-waited subjects in polymer chemistry and macromolecular …

Glycopolymer nanobiotechnology

Y Miura, Y Hoshino, H Seto - Chemical reviews, 2016 - ACS Publications
Molecular recognition plays an important role in living systems. 1, 2 Representative
molecular recognitions in living organisms are saccharide− protein, protein− protein, and …