Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds
R Cannalire, S Pelliccia, L Sancineto… - Chemical Society …, 2021 - pubs.rsc.org
The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …
to speed up the identification of structure–activity relationships (SARs) and to optimize …
Photochemical aerobic upcycling of polystyrene plastics to commodity chemicals using anthraquinone as the photocatalyst
Since the United Nations set goals dealing with climate change, the chemical industry has
focused on recycling the already-used polymers, targeting the reinsertion of plastic waste to …
focused on recycling the already-used polymers, targeting the reinsertion of plastic waste to …
Photochemical aerobic oxidation of sulfides to sulfoxides: the crucial role of wavelength irradiation
The sulfoxide moiety is recognized as one of the most important groups in organic and
medicinal chemistry. Many efforts worldwide focus on developing novel and sustainable …
medicinal chemistry. Many efforts worldwide focus on developing novel and sustainable …
Visible-light-induced decarboxylative acylation of quinoxalin-2 (1 H)-ones with α-oxo carboxylic acids under metal-, strong oxidant-and external photocatalyst-free …
LY Xie, YS Bai, XQ Xu, X Peng, HS Tang, Y Huang… - Green …, 2020 - pubs.rsc.org
A mild and eco-friendly visible-light-induced decarboxylative acylation of quinoxalin-2 (1H)-
ones and α-oxo carboxylic acids with ambient air as the sole oxidant at room temperature …
ones and α-oxo carboxylic acids with ambient air as the sole oxidant at room temperature …
Light-promoted oxidation of aldehydes to carboxylic acids under aerobic and photocatalyst-free conditions
CS Batsika, C Koutsilieris, GS Koutoulogenis… - Green …, 2022 - pubs.rsc.org
The development of green and sustainable methods for the conversion of aldehydes to
carboxylic acids is of high academic and industrial interest. We demonstrate herein a …
carboxylic acids is of high academic and industrial interest. We demonstrate herein a …
Visible-Light Photoredox-Catalyzed Divergent 1, 2-Diacylation and Hydroacylation of Alkenes with Carboxylic Acid Anhydride
Y Zhou, L Zhao, M Hu, XH Duan, L Liu - Organic Letters, 2023 - ACS Publications
A photoredox-catalyzed divergent 1, 2-dicarbonylation and hydroacylation of alkenes with
acid anhydride is presented. This approach offers a mild and efficient entry to 1, 4-dicarbonyl …
acid anhydride is presented. This approach offers a mild and efficient entry to 1, 4-dicarbonyl …
Photochemical metal-free aerobic oxidation of thiols to disulfides
N Spiliopoulou, CG Kokotos - Green Chemistry, 2021 - pubs.rsc.org
Thiol oxidation to disulfides is an area of great importance in organic synthesis, both for
synthetic and biological purposes. Herein, we report a mild, inexpensive and green …
synthetic and biological purposes. Herein, we report a mild, inexpensive and green …
Direct 1, 2‐Dicarbonylation of Alkenes towards 1, 4‐Diketones via Photocatalysis
Dicarbonyl compounds are intriguing motifs and versatile precursors in numerous
pharmaceutical molecules and bioactive natural compounds. Direct incorporation of two …
pharmaceutical molecules and bioactive natural compounds. Direct incorporation of two …
Photoredox-enabled chromium-catalyzed alkene diacylations
J Liu, LQ Lu, Y Luo, W Zhao, PC Sun, W Jin, X Qi… - ACS …, 2022 - ACS Publications
Transition-metal-catalyzed cross-coupling reactions are a powerful tool to construct carbon–
carbon bonds in modern synthetic chemistry. Chromium catalysis is much less developed …
carbon bonds in modern synthetic chemistry. Chromium catalysis is much less developed …