Electronic control over site-selectivity in hydrogen atom transfer (HAT) based C (sp 3)–H functionalization promoted by electrophilic reagents
M Galeotti, M Salamone, M Bietti - Chemical Society Reviews, 2022 - pubs.rsc.org
The direct functionalization of C (sp3)–H bonds represents one of the most investigated
approaches to develop new synthetic methodology. Among the available strategies for …
approaches to develop new synthetic methodology. Among the available strategies for …
Regioselective Transition‐Metal‐Free C(sp2)−H Borylation: A Subject of Practical and Ongoing Interest in Synthetic Organic Chemistry
S Rej, N Chatani - Angewandte Chemie International Edition, 2022 - Wiley Online Library
Considerable advances have been made in the area of C− H functionalization in the last few
decades. A number of approaches including both directed and nondirected strategies have …
decades. A number of approaches including both directed and nondirected strategies have …
Nickel and palladium catalysis: Stronger demand than ever
VM Chernyshev, VP Ananikov - Acs Catalysis, 2022 - ACS Publications
Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …
Modelling the effect of renewable energy and public-private partnership in testing EKC hypothesis: evidence from methods moment of quantile regression
Global warming is creating a distressing situation around the globe and, accordingly,
requires substantial solutions. Among the potential solutions are shifting towards renewable …
requires substantial solutions. Among the potential solutions are shifting towards renewable …
Weak-coordination in C–H bond functionalizations catalyzed by 3d metals
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …
Remote steric control for undirected meta-selective C–H activation of arenes
Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …
C–H bond functionalization by high-valent cobalt catalysis: current progress, challenges and future perspectives
L Lukasevics, A Cizikovs, L Grigorjeva - Chemical Communications, 2021 - pubs.rsc.org
Over the last decade, high-valent cobalt catalysis has earned a place in the spotlight as a
valuable tool for C–H activation and functionalization. Since the discovery of its unique …
valuable tool for C–H activation and functionalization. Since the discovery of its unique …
Gold-catalyzed C (sp 3)–H bond functionalization
J Xie, C Pan, A Abdukader, C Zhu - Chemical Society Reviews, 2014 - pubs.rsc.org
C–H bonds are ubiquitous in organic molecules. Homogenous gold-catalyzed direct
functionalization of unsaturated C–H bonds has emerged as a powerful method in our …
functionalization of unsaturated C–H bonds has emerged as a powerful method in our …
Achiral Cp* Rh (III)/chiral lewis base cooperative catalysis for enantioselective cyclization via C–H activation
An enantioselective [4+ 3] cyclization via C (sp2)–H activation with a cooperative catalytic
system consisting of a Cp* Rh (III) complex and a chiral Lewis base is described. An α, β …
system consisting of a Cp* Rh (III) complex and a chiral Lewis base is described. An α, β …
A combined computational and experimental study of Rh-catalyzed C–H silylation with silacyclobutanes: insights leading to a more efficient catalyst system
The study of new C–H silylation reagents and reactions remains an important topic. We
reported that under Rh catalysis, silacyclobutanes (SCBs) for the first time were able to react …
reported that under Rh catalysis, silacyclobutanes (SCBs) for the first time were able to react …