Herein, we report the copper-catalyzed dehydrogenative C (sp2)–N bond formation of 4-
pentenamides via nitrogen-centered radicals. This reaction provides a straightforward and …

Over the past years, Pd (II)-catalyzed oxidative couplings have enabled the construction of
molecular scaffolds with high structural diversity via C–C, C–N and C–O bond-forming …

A visible light promoted process for desulfonylation of N-sulfonylamides and-amines has
been developed, in which 1, 3-dimethyl-2-hydroxynaphthylbenzimidazoline (HONap-BIH) …

Amines are widely applied in the chemical and pharmaceutical industries, and the
development of synthetic methods for their preparation is driven by their importance. The …

An unprecedented N-substituent of the amide was found to be crucial for the successful
annulation to establish 2-azabicyclo [3.3. 1] nonane and other ring skeletons in good yield …

Unconventional modification of palladium-catalyzed oxidative amination where a furan ring
serves as a masked olefin is described. The designed chemical process provides 2-(2 …

A study of the palladium (II)‐catalyzed cyclization of unsaturated N‐sulfonylamides was
undertaken, using (diacyloxyiodo) benzenes as terminal oxidizing agents. Different …

In this full account, the evolution of a synthetic strategy was detailed from a nitroso-ene
cyclization to an aza-Wacker reaction for ring construction in the syntheses of melinonine-E …

n‐Bu4NI/K2S2O8‐mediated C‐N coupling between aldehydes and amides is reported. A
strong electronic effect is observed on the aromatic aldehyde substrates. The …

In general, alkylpalladium intermediates containing a syn β‐hydrogen atom are expected to
undergo β–hydride elimination preferentially. However, this study unveils a new mechanistic …