Cyclotriphosphazene based materials: Structure, functionalization and applications

D Wang, X Xu, Y Qiu, J Wang, L Meng - Progress in Materials Science, 2024 - Elsevier
In recent decades, cyclotriphosphazene (CTP) and its derivatives have garnered significant
attention due to their exceptional physical and chemical properties, such as remarkable …

Cyclophosphazene-based multi-site coordination ligands

V Chandrasekhar, P Thilagar, BM Pandian - Coordination Chemistry …, 2007 - Elsevier
This review deals with the recent developments in the design, assembly and utility of
cyclophosphazene-based ligands. The reactive periphery of the chlorocyclophosphazenes …

Novel spirocyclic phosphazene-based epoxy resin for halogen-free fire resistance: synthesis, curing behaviors, and flammability characteristics

J Sun, X Wang, D Wu - ACS applied materials & interfaces, 2012 - ACS Publications
A novel halogen-free fire resistant epoxy resin with pendent spiro-cyclotriphosphazene
groups was designed and synthesized via a three-step synthetic pathway. The chemical …

Novel cyclotriphosphazene-based epoxy compound and its application in halogen-free epoxy thermosetting systems: Synthesis, curing behaviors, and flame …

H Liu, X Wang, D Wu - Polymer degradation and stability, 2014 - Elsevier
A novel cyclotriphosphazene-based epoxy compound (PN-EPC) as a halogen-free reactive-
type flame retardant was synthesized via a two-step synthetic route. The chemical structures …

Polyphosphazenes: A review

M Gleria, R De Jaeger - New Aspects in Phosphorus Chemistry V: -/-, 2005 - Springer
In this paper the synthesis, properties and applications of poly (organophosphazenes) have
been highlighted. Five different classes of macromolecules have been described, ie …

(Amino) cyclophosphazenes as multisite ligands for the synthesis of antitumoral and antibacterial silver (I) complexes

E Gascón, S Maisanaba, I Otal, E Valero… - Inorganic …, 2020 - ACS Publications
The reactivity of the multisite (amino) cyclotriphosphazene ligands,[N3P3 (NHCy) 6] and
[N3P3 (NHCy) 3 (NMe2) 3], has been explored in order to obtain silver (I) …

Phosphorus− Nitrogen Compounds. 18. Syntheses, stereogenic properties, structural and electrochemical investigations, biological activities, and DNA interactions of …

N Asmafiliz, Z Kılıç, A Öztürk, T Hökelek… - Inorganic …, 2009 - ACS Publications
The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6, with mono-(1 and 2) and
bisferrocenyldiamines (3− 5), FcCH2NH (CH2) n NHR1 (R1= H or FcCH2−), produce mono …

Synthesis and flame retardant efficacy of hexakis (3-(triethoxysilyl) propyloxy) cyclotriphosphazene/silica coatings for cotton fabrics

M Dutkiewicz, M Przybylak, R Januszewski… - Polymer Degradation …, 2018 - Elsevier
The development of novel flame retardants for cotton textiles that form a stable layer on the
textile fiber is of high economical and practical relevance. Hexakis (3-(triethoxysilyl) …

Phosphorus–nitrogen compounds. Part 54. syntheses of chiral amino-4-fluorobenzyl-spiro (N/O) cyclotriphosphazenes: structural and stereogenic properties

ÖF Mutlu, A Binici, A Okumuş, G Elmas… - New Journal of …, 2021 - pubs.rsc.org
Although tetrahedrally coordinated pendant-armed heterocyclic phosphazenes are
considerably stable, the stereogenic properties of their inorganic ring systems are much less …

The comparative reactions of 2‐cis‐4‐ansa and spiro cyclotetraphosphazenes with difunctional ligands: Structural and stereogenic properties, electrochemical …

A Okumuş, G Elmas, Z Kılıç, A Binici… - Applied …, 2021 - Wiley Online Library
In this study, two kinds of compounds, namely, mono‐ferrocenyl‐2‐cis‐4‐dichloro‐ansa‐(2,
4‐ansa; 3) and mono‐ferrocenyl‐spiro‐(spiro; 4) hexachlorocyclotetraphosphazenes, were …