Bio-based polymers with performance-advantaged properties

RM Cywar, NA Rorrer, CB Hoyt, GT Beckham… - Nature Reviews …, 2022 - nature.com
Bio-based compounds with unique chemical functionality can be obtained through selective
transformations of plant and other non-fossil, biogenic feedstocks for the development of …

Synthesis and alignment of liquid crystalline elastomers

KM Herbert, HE Fowler, JM McCracken… - Nature Reviews …, 2022 - nature.com
Liquid crystalline elastomers (LCEs) are crosslinked polymer networks that combine the
elastic properties of rubber with the anisotropic properties of liquid crystals. Multifunctionality …

A biodegradable, waterproof, and thermally processable cellulosic bioplastic enabled by dynamic covalent modification

G Zhou, H Zhang, Z Su, X Zhang, H Zhou… - Advanced …, 2023 - Wiley Online Library
The growing environmental concern over petrochemical‐based plastics continuously
promotes the exploration of green and sustainable substitute materials. Compared with …

Disulfide-mediated reversible polymerization toward intrinsically dynamic smart materials

Q Zhang, DH Qu, BL Feringa… - Journal of the American …, 2022 - ACS Publications
The development of a dynamic chemistry toolbox to endow materials dynamic behavior has
been key to the rational design of future smart materials. The rise of supramolecular and …

Dynamic and reconfigurable materials from reversible network interactions

MJ Webber, MW Tibbitt - Nature Reviews Materials, 2022 - nature.com
Polymer materials provide solutions to some of the most pressing environmental,
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …

Dynamic covalent polymer networks: a molecular platform for designing functions beyond chemical recycling and self-healing

N Zheng, Y Xu, Q Zhao, T Xie - Chemical Reviews, 2021 - ACS Publications
Dynamic covalent polymer networks (DCPN) have historically attracted attention for their
unique roles in chemical recycling and self-healing, which are both relevant for sustainable …

Dynamic crosslinking compatibilizes immiscible mixed plastics

RW Clarke, T Sandmeier, KA Franklin, D Reich… - Nature, 2023 - nature.com
The global plastics problem is a trifecta, greatly affecting environment, energy and climate,,–.
Many innovative closed/open-loop plastics recycling or upcycling strategies have been …

Biobased vitrimers: Towards sustainable and adaptable performing polymer materials

MA Lucherelli, A Duval, L Avérous - Progress in Polymer Science, 2022 - Elsevier
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …

Strong and tough supramolecular covalent adaptable networks with room‐temperature closed‐loop recyclability

Z Zhang, D Lei, C Zhang, Z Wang, Y Jin… - Advanced …, 2023 - Wiley Online Library
Abstract Development of closed‐loop chemically recyclable plastics (CCRPs) that can be
widely used in daily life can be a fundamental solution to the global plastic waste crisis …

Defining the macromolecules of tomorrow through synergistic sustainable polymer research

FM Haque, JSA Ishibashi, CAL Lidston, H Shao… - Chemical …, 2022 - ACS Publications
Transforming how plastics are made, unmade, and remade through innovative research and
diverse partnerships that together foster environmental stewardship is critically important to …