Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …
them at the forefront of the race toward high-temperature single-molecule magnets and …
Unraveling the contributions to spin–lattice relaxation in kramers single-molecule magnets
The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …
unique insights into its chemical environment and the relation between electronic structure …
Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes
AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …
been actively studied for potential applications in the new generation of high-density data …
Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt (II) complexes with zero-field hidden single-molecule magnet behaviour: the …
A Landart-Gereka, MM Quesada-Moreno… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The complexes [Co (L)] X· S (X= CoCl42−, S= CH3CN (1); X= ZnCl42−, S= CH3OH (2)),[Co
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
Air-stable four-coordinate cobalt (II) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic …
SK Gupta, SV Rao, S Demeshko, S Dechert, E Bill… - Chemical …, 2023 - pubs.rsc.org
For single-ion magnets (SIMs), understanding the effects of the local coordination
environment and ligand field on magnetic anisotropy is key to controlling their magnetic …
environment and ligand field on magnetic anisotropy is key to controlling their magnetic …
Ab initio prediction of tunneling relaxation times and effective demagnetization barriers in kramers lanthanide single-molecule magnets
D Aravena - The Journal of Physical Chemistry Letters, 2018 - ACS Publications
Single-molecule magnets (SMMs) are promising candidates for molecule-based quantum
information devices. Their main limitation is their cryogenic operative temperature. To …
information devices. Their main limitation is their cryogenic operative temperature. To …
A Survey of the Angular Distortion Landscape in the Coordination Geometries of High-Spin Iron (II) 2, 6-Bis (pyrazolyl) pyridine Complexes
I Capel Berdiell, E Michaels, OQ Munro… - Inorganic …, 2024 - ACS Publications
Reaction of 2, 4, 6-trifluoropyridine with sodium 3, 4-dimethoxybenzenethiolate and 2 equiv
of sodium pyrazolate in tetrahydrofuran at room temperature affords 4-(3, 4 …
of sodium pyrazolate in tetrahydrofuran at room temperature affords 4-(3, 4 …
Structure-property correlation in stabilizing axial magnetic anisotropy in octahedral Co (II) complexes
Stabilizing an easy axis of magnetization in an octahedral Co (II) complex is an extremely
challenging task, which is evident from reports that more than 90% possess easy-plane …
challenging task, which is evident from reports that more than 90% possess easy-plane …
Spin-Crossover in a New Iron (II)/Di (pyrazolyl) pyridine Complex with a Terpyridine Embrace Lattice. Thermally Induced Excited Spin State Trapping and Clarification …
E Michaels, I Capel Berdiell, HB Vasili… - Crystal Growth & …, 2022 - ACS Publications
The complex salts [Fe L 2] X2 (1X 2; L= 2, 6-di {4-fluoropyrazol-1-yl} pyridine; X–= BF4–or
ClO4–) exhibit abrupt spin-transitions with narrow thermal hysteresis, at T 1/2= 164 K (X …
ClO4–) exhibit abrupt spin-transitions with narrow thermal hysteresis, at T 1/2= 164 K (X …