Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

The development of new strategies and chemical reactions continues to be a major focus of
research efforts in the modern synthetic organic community. 1 Of the various types of …

Low-valent early transition metals are often intrinsically highly reactive as a result of their
strong propensity toward oxidation to more stable high-valent states. Harnessing these …

A photoredox-catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum
oxidation cascade of cycloketone oxime esters and styrenes in DMSO is described. This …

This review highlights the recent applications of titanocene (III) complexes in the field of
natural product synthesis from the seminal precedents to the development of modern …

By merging cross-electrophile coupling and C–C bond cleavage, we developed a Ni-
catalyzed electrophilic ring opening of cycloketone oxime esters with aromatic acid chlorides …

Described herein is a catalytic asymmetric total synthesis of (−)-actinophyllic acid, with the
key step being a chiral phosphine-catalyzed [3+ 2] annulation between an imine and an …

The development of Green Chemistry inevitably involves the development of green
reagents. In this review, we highlight that Cp2TiCl is a reagent widely used in radical and …

In the last two decades, titanocene monochloride has been postulated as a monoelectronic
transfer reagent capable of catalyzing an important variety of chemical transformations. In …

By exploiting solvent and anion effects,[Cp2Ti]+ complexes for atom‐economical catalysis in
single‐electron steps were developed and applied for the first time. These complexes …