Multiscale nuclear magnetic relaxation dispersion of complex liquids in bulk and confinement

JP Korb - Progress in Nuclear Magnetic Resonance …, 2018 - Elsevier
The nuclear magnetic relaxation dispersion (NMRD) technique consists of measurement of
the magnetic-field dependence of the longitudinal nuclear-spin-lattice relaxation rate 1/T 1 …

Fractionation and characterization of petroleum asphaltene: focus on metalopetroleomics

F Zheng, Q Shi, GS Vallverdu, P Giusti, B Bouyssiere - Processes, 2020 - mdpi.com
Asphaltenes, as the heaviest and most polar fraction of petroleum, have been characterized
by various analytical techniques. A variety of fractionation methods have been carried out to …

Effect of solvent on the adsorption behavior of asphaltene on silica surface: A molecular dynamic simulation study

N Lu, X Dong, Z Chen, H Liu, W Zheng… - Journal of Petroleum …, 2022 - Elsevier
In recent years, the hybrid thermal-solvent process has been widely applied to improve the
recovery performance of steam injection processes in heavy oil reservoirs. In this paper, the …

Advances and challenges in the molecular characterization of petroporphyrins

AM McKenna, ML Chacón-Patiño… - Energy & …, 2021 - ACS Publications
Petroporphyrins, geoporphyrins, or metalloporphyrins are the original petroleum biomarkers,
identified by Alfred Treibs more than a century ago and the first molecular evidence for the …

Elucidating the geometric substitution of petroporphyrins by spectroscopic analysis and atomic force microscopy molecular imaging

Y Zhang, F Schulz, BMK Rytting, CC Walters… - Energy & …, 2019 - ACS Publications
Determination of the molecular structures of petroporphyrins has been crucial to understand
the diagenetic pathways and maturation of petroleum. However, these studies have been …

Asphaltene aggregation studied by molecular dynamics simulations: role of the molecular architecture and solvents on the supramolecular or colloidal behavior

H Santos Silva, A Alfarra, G Vallverdu, D Bégué… - Petroleum Science, 2019 - Springer
Asphaltene aggregation is a subject under vivid discussion: There are several parameters
one needs to determine before its behavior can be mastered and better target solutions can …

Resin–Paraffin Aggregation Processes in Waxy Oil Revealed by Vanadyl Porphyrin Spin Probe

SN Trukhan, EV Morozov, ON Martyanov - Energy & Fuels, 2023 - ACS Publications
The work demonstrates the great potential of using a vanadyl porphyrin probe to study resin–
paraffin aggregation processes in oils. The dynamics and polarity of the local environment of …

Oil spills characteristics, detection, and recovery methods: A systematic risk-based view

ACSV de Negreiros, ID Lins, CBS Maior… - Journal of Loss …, 2022 - Elsevier
Petroleum is still the most important energy source globally and essential to daily human
activities. Its exploration in deep waters and the logistics-related operations present the risk …

Molecular dynamics and proton hyperpolarization via synthetic and crude oil porphyrin complexes in solid and solution states

B Gizatullin, M Gafurov, F Murzakhanov, A Vakhin… - Langmuir, 2021 - ACS Publications
The use of vanadyl porphyrins either in synthetic compounds or naturally occurring in
asphaltenes is investigated as a source of proton hyperpolarization via dynamic nuclear …

Non-covalent π-stacking interactions between asphaltene and porphyrin in bitumen

M Mousavi, EH Fini - Journal of Chemical Information and …, 2020 - ACS Publications
In recent years, the dominant organizing role of non-covalent π-stacking interactions in the
association of asphaltenes and porphyrins was criticized and replaced with cooperative …