Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

Radical cascade reactions are an attractive tool for the rapid construction of complex
molecular architectures. Although a large number of powerful radical cascades have been …

The field of strain‐driven, radical formal cycloadditions is experiencing a surge in activity
motivated by a renaissance in free radical chemistry and growing demand for sp3‐rich ring …

Racemization is considered to be an intrinsic stereochemical feature of free radical
chemistry as can be seen in traditional radical halogenation reactions of optically active …

Donor-substituted diazo reagents, generated in situ from sulfonyl hydrazones in the
presence of base, can serve as suitable radical precursors for Co (II)-based metalloradical …

Radical reactions hold a number of inherent advantages in organic synthesis that may
potentially impact the planning and practice for construction of organic molecules. However …

New catalytic strategies that leverage single-electron redox events have provided chemists
with useful tools for solving synthetic problems. In this context, Ti offers opportunities that are …

Since Friedrich Wöhler's groundbreaking synthesis of urea in 1828, organic synthesis over
the past two centuries has predominantly relied on the exploration and utilization of …

Both arylsulfonyl and alkylsulfonyl azides can be effectively activated by the cobalt (II)
complexes of D 2-symmetric chiral amidoporphyrins for enantioselective radical 1, 5-C–H …

From its humble origins as a mere 'chemical curiosity,'radical chemistry has developed into
one of the most powerful tools for preparative organic synthesis. Initially considered too …