Replacing fossil fuels with energy sources and carriers that are sustainable, environmentally
benign, and affordable is amongst the most pressing challenges for future socio-economic …

Only rarely have polyoxometalates been found to form core–shell nanoclusters. Here, we
succeeded in isolating a series of rare giant and all‐inorganic core–shell cobalt …

An unprecedented aggregate formed by two bismuth–antimony–europium cluster-imbedded
tungsten-oxo clusters and one Krebs-type polyoxotungstate linker [H2N (CH3) 2] 14Na30H6 …

Water oxidation is a bottleneck reaction for the establishment of solar-to-fuel energy
conversion systems. Earth-abundant metal-based polyoxometalates are promising …

The water oxidation half-reaction is vital in numerous alternative-energy blueprints and
technologies since it can provide four protons and four electrons necessary for transforming …

The assembly of heterometallic cluster substituted polyoxometalates (POMs) remains a
great challenge for inorganic synthetic chemistry up to now. Herein, a series of 5p–4f …

Production of hydrogen through water splitting is one of the green and the most practical
solutions to cope with the energy crisis and greenhouse effect. However, oxygen evolution …

At near neutral to basic pH, hydrolysis‐induced aggregation to insoluble bulk iron‐oxide is
often regarded as the pitfalls of molecular iron clusters. Iron‐oxide nanocrystals are …

Mixed 3d metal oxides are some of the most promising water oxidation catalysts (WOCs), but
it is very difficult to know the locations and percent occupancies of different 3d metals in …

A family of multinuclear rare-earth (RE)-implanted H2tart2–-functionalized selenotungstates
(STs)[H2N (CH3) 2] 13H {[W2O5 (OH) 2 (H2tart) 2](H2tart){[W3O6RE2 (H2O) 6][SeW9O33] …