A guide to the synthesis of block copolymers using reversible-addition fragmentation chain transfer (RAFT) polymerization

DJ Keddie - Chemical Society Reviews, 2014 - pubs.rsc.org
The discovery of reversible-deactivation radical polymerization (RDRP) has provided an
avenue for the synthesis of a vast array of polymers with a rich variety of functionality and …

Controlled/living radical polymerization: Features, developments, and perspectives

WA Braunecker, K Matyjaszewski - Progress in polymer science, 2007 - Elsevier
Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

Living radical polymerization by the RAFT process

G Moad, E Rizzardo, SH Thang - Australian journal of chemistry, 2005 - CSIRO Publishing
This paper presents a review of living radical polymerization achieved with thiocarbonylthio
compounds [ZC (= S) SR] by a mechanism of reversible addition–fragmentation chain …

Advances in RAFT polymerization: the synthesis of polymers with defined end-groups

G Moad, YK Chong, A Postma, E Rizzardo, SH Thang - Polymer, 2005 - Elsevier
This paper provides an overview and discusses some recent developments in radical
polymerization with reversible addition–fragmentation chain transfer (RAFT polymerization) …

Macromolecular design via reversible addition–fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization

S Perrier, P Takolpuckdee - Journal of Polymer Science Part A …, 2005 - Wiley Online Library
Among the living radical polymerization techniques, reversible addition–fragmentation chain
transfer (RAFT) and macromolecular design via the interchange of xanthates (MADIX) …

Controlled/living radical polymerization in dispersed systems

PB Zetterlund, Y Kagawa, M Okubo - Chemical reviews, 2008 - ACS Publications
1.2 Background Radical polymerization is of enormous industrial importance; approximately
50% of all commercial polymers are produced by radical polymerization.(23) The process is …

Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization of Vinyl Acetate and N-Vinylpyrrolidinone: Kinetic …

S Shanmugam, J Xu, C Boyer - Macromolecules, 2014 - ACS Publications
Photoinduced electron transfer–reversible addition–fragmentation chain transfer (PET-
RAFT) polymerization was employed for the polymerization of unconjugated monomers …

Building nanostructures using RAFT polymerization

C Boyer, MH Stenzel, TP Davis - Journal of Polymer Science …, 2011 - Wiley Online Library
Reversible addition fragmentation chain transfer (RAFT) polymerization is one of the most
extensively studied controlled/living radical polymerization methods that has been used to …

Experimental Requirements for an Efficient Control of Free‐Radical Polymerizations via the Reversible Addition‐Fragmentation Chain Transfer (RAFT) Process

A Favier, MT Charreyre - Macromolecular Rapid …, 2006 - Wiley Online Library
Reversible addition‐fragmentation chain transfer (RAFT) polymerization is a recent and very
versatile controlled radical polymerization technique that has enabled the synthesis of a …

A photoinitiation system for conventional and controlled radical polymerization at visible and NIR wavelengths

N Corrigan, J Xu, C Boyer - Macromolecules, 2016 - ACS Publications
We report for the first time the use of phthalocyanine compounds, in conjunction with the
common solvent N-methyl-2-pyrrolidone (NMP), as a photoinitiation system for radical …