Activation of dinitrogen by polynuclear metal complexes
Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …
by which this fixation occurs have been a longstanding and significant research focus within …
Activation of Molecular Nitrogen: Coordination, Cleavage and Functionalization of N2 Mediated By Metal Complexes
Recent developments in the activation and reactivity of coordinated dinitrogen are reviewed.
Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogen …
Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogen …
Benchmark Study of Density Functional Theory Methods in Geometry Optimization of Transition Metal–Dinitrogen Complexes
C Zhao, R Wu, S Zhang, X Hong - The Journal of Physical …, 2023 - ACS Publications
The current benchmark study is focused on determining the most precise theoretical method
for optimizing the geometry of transition metal–dinitrogen complexes. To accomplish this …
for optimizing the geometry of transition metal–dinitrogen complexes. To accomplish this …
Catalytic ammonia oxidation to dinitrogen by hydrogen atom abstraction
P Bhattacharya, ZM Heiden… - Angewandte Chemie …, 2019 - Wiley Online Library
Catalysts for the oxidation of NH3 are critical for the utilization of NH3 as a large‐scale
energy carrier. Molecular catalysts capable of oxidizing NH3 to N2 are rare. This report …
energy carrier. Molecular catalysts capable of oxidizing NH3 to N2 are rare. This report …
Methylene-Linked Bis-NHC Half-sandwich ruthenium complexes: Binding of small molecules and catalysis toward ketone transfer hydrogenation
JM Botubol-Ares, S Cordón-Ouahhabi… - …, 2021 - ACS Publications
The complex [Cp* RuCl (COD)] reacts with L H2Cl2 (L= bis (3-methylimidazol-2-ylidene))
and LiBu n in tetrahydrofuran at 65° C furnishing the bis-carbene derivative [Cp* RuCl …
and LiBu n in tetrahydrofuran at 65° C furnishing the bis-carbene derivative [Cp* RuCl …
Dinitrogen Activation of Cyclopentadienyl-Phosphine–Iron Complexes of Three Different Valences
A series of structurally well-defined iron–dinitrogen complexes (L Fe–N2) bearing
cyclopentadienyl-phosphine ligands (L) were synthesized and analyzed by single-crystal X …
cyclopentadienyl-phosphine ligands (L) were synthesized and analyzed by single-crystal X …
Half-sandwich ruthenium (II) picolyl-NHC complexes: synthesis, characterization, and catalytic activity in transfer hydrogenation reactions
Pentamethylcyclopentadienyl ruthenium (II) complexes with picolyl-functionalized N-
heterocyclic carbenes [(η5-C5Me5) Ru (L)(CH3CN)][PF6](L= 3-methyl-1-(2-picolyl) imidazol …
heterocyclic carbenes [(η5-C5Me5) Ru (L)(CH3CN)][PF6](L= 3-methyl-1-(2-picolyl) imidazol …
Origin of Stability and Inhibition of Cooperative Alkyne Hydrofunctionalization Catalysts
DE Chapple, PD Boyle, JM Blacquiere - ChemCatChem, 2021 - Wiley Online Library
New entries to the [Ru (Cp/Cp*)(PR2NR′ 2)(MeCN)] PF6 catalyst family were synthesized,
including a Cp complex (R= Cy; R′= Ph) and two Cp* complexes (R= Cy, Ph; R′= Ph) …
including a Cp complex (R= Cy; R′= Ph) and two Cp* complexes (R= Cy, Ph; R′= Ph) …
A CH 2 Cl 2 complex of a [Rh (pincer)]+ cation
A CH 2 Cl 2 complex of a [Rh(pincer)] + cation - Dalton Transactions (RSC Publishing) DOI:10.1039/C5DT00481K
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Low-valent ruthenium complexes of the non-innocent 2, 6-bis (imino) pyridine ligand
M Gallagher, NL Wieder, VK Dioumaev… - …, 2010 - ACS Publications
A series of low-valent ruthenium complexes bearing 2, 6-bis (imino) pyridyl (“[N3]”) ligands
has been synthesized and characterized. Reduction of [N3] RuCl2 (C2H4)([N3xyl]= 2, 6 …
has been synthesized and characterized. Reduction of [N3] RuCl2 (C2H4)([N3xyl]= 2, 6 …