A long-standing challenge in synthetic chemistry is the direct, selective functionalization of
alkyl, alkenyl, and aryl CH bonds. Much research has been devoted to the selective …

A general aim of transition metal-catalysed organic synthesis is carbon–carbon (C–C) bond
formation. In this respect, the Pd-catalysed Suzuki–Miyaura (SM) coupling reaction 1 is one …

Suzuki− Miyaura coupling reactions of aryl and heteroaryl halides with aryl-, heteroaryl-and
vinylboronic acids proceed in very good to excellent yield with the use of 2-(2 ', 6 ' …

It has been well-documented that catalytic asymmetric synthesis is a field of great
importance in its practical usefulness as well as its scientific interest. 1 Among several types …

In the past 20 years there has been dramatic growth in the use of transition metal catalysts in
synthetically important organic transformations. Recently, increased attention has been paid …

Organometallic reagents (RM) are of increasing importance not only for organometallic
chemists but also in organic chemistry and pharmaceutical synthesis and to access organic …

The author's work on (α-haloalkyl) boronic esters as reagents for asymmetric synthesis is
reviewed. Diastereomeric ratios exceeding 1000 can be achieved with this chemistry, and …

The rhodium catalysed conjugate addition of organometallics to activated alkenes is a
powerful synthetic tool for establishing new carbon–carbon bonds often with high …

The metal‐catalyzed hydroboration reaction provides access to functionalized organoboron
derivatives that cannot be easily prepared using traditional reagents. New developments in …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …