Emerging applications for living crystallization-driven self-assembly

L MacFarlane, C Zhao, J Cai, H Qiu, I Manners - Chemical Science, 2021 - pubs.rsc.org
The use of crystallization as a tool to control the self-assembly of polymeric and molecular
amphiphiles in solution is attracting growing attention for the creation of non-spherical …

Confined crystallization of polymeric materials

RM Michell, AJ Müller - Progress in Polymer Science, 2016 - Elsevier
The interest in confined crystallization has greatly increased with the development and
progress of nanotechnology applications. Polymeric confined crystallization has been …

50th Anniversary Perspective: Functional Nanoparticles from the Solution Self-Assembly of Block Copolymers

U Tritschler, S Pearce, J Gwyther, GR Whittell… - …, 2017 - ACS Publications
This Perspective outlines recent advances concerning the formation and potential uses of
block copolymer micelles, a class of soft-matter-based nanoparticles of growing importance …

Monodisperse cylindrical micelles by crystallization-driven living self-assembly

JB Gilroy, T Gädt, GR Whittell, L Chabanne… - Nature …, 2010 - nature.com
Non-spherical nanostructures derived from soft matter and with uniform size—that is,
monodisperse materials—are of particular utility and interest, but are very rare outside the …

Crystallization assisted self-assembly of semicrystalline block copolymers

WN He, JT Xu - Progress in Polymer Science, 2012 - Elsevier
The self-assembly of block copolymers (BCPs) in the presence of crystallization as the
second driving force is reviewed, for BCPs in the bulk, thin films, single crystals and micelles …

A guide to supramolecular polymerizations

M Hartlieb, EDH Mansfield, S Perrier - Polymer Chemistry, 2020 - pubs.rsc.org
Supramolecular polymers or fibers are non-covalent assemblies of unimeric building blocks
connected by secondary interactions such as hydrogen bonds or π–π interactions. Such …

Cylindrical micelles from the living crystallization-driven self-assembly of poly (lactide)-containing block copolymers

N Petzetakis, AP Dove, RK O'Reilly - Chemical Science, 2011 - pubs.rsc.org
The synthesis and self-assembly of poly (lactide)-b-poly (acrylic acid) and poly (lactide)-b-
poly (dimethylaminoethylacrylate) block copolymers by a combination of ring-opening …

Solid micellar Ru single-atom catalysts for the water-free hydrogenation of CO2 to formic acid

Q Wang, S Santos, CA Urbina-Blanco… - Applied Catalysis B …, 2021 - Elsevier
The catalytic hydrogenation of CO 2 to formic acid is one of the most promising pathways
towards a renewable hydrogen-storage system. The reaction is usually performed in …

[HTML][HTML] Confinement effects on polymer crystallization: From droplets to alumina nanopores

RM Michell, I Blaszczyk-Lezak, C Mijangos, AJ Müller - Polymer, 2013 - Elsevier
We review previous works on polymer confined crystallization employing strategies that
allow confinement to go from the micron to the nanometer scale: droplets, blends, block …

General pathway toward crystalline-core micelles with tunable morphology and corona segregation

J Schmelz, M Karg, T Hellweg, H Schmalz - ACS nano, 2011 - ACS Publications
We present a general mechanism for the solution self-assembly of crystalline-core micelles
(CCMs) from triblock copolymers bearing a semicrystalline polyethylene (PE) middle block …