The reactions of dimethyl carbonate and its derivatives

P Tundo, M Musolino, F Aricò - Green chemistry, 2018 - pubs.rsc.org
The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry
and academia to develop of chlorine-free methodologies focused on the use of CO2 and …

Recent advances in S-functionalized N-heterocyclic carbene ligands: From the synthesis of azolium salts and metal complexes to applications

C Fliedel, P Braunstein - Journal of Organometallic Chemistry, 2014 - Elsevier
This review summarizes the recent progress in the field of S-functionalized N-heterocyclic
carbene ligands and their metal complexes. The syntheses of the azolium precursors and of …

Dinuclear Zinc–N‐Heterocyclic Carbene Complexes for Either the Controlled Ring‐Opening Polymerization of Lactide or the Controlled Degradation of Polylactide …

C Fliedel, D Vila‐Viçosa, MJ Calhorda… - …, 2014 - Wiley Online Library
We describe the synthesis of the new Zn–N‐heterocyclic carbene (NHC) alkoxide
complexes [(S, CNHC) ZnCl (OBn)] 2 (5) and [(O, CNHC) ZnCl (OBn)] 2 (6) for use as ring …

N-heterocyclic carbenes as bridgehead donors in metal pincer complexes

F He, KP Zois, D Tzeli, AA Danopoulos… - Coordination Chemistry …, 2024 - Elsevier
Rigid terdentate 'pincer'ligands containing a bridgehead N-heterocyclic carbene (NHC)
donor attract considerable interest as spectators in transition metal complexes with broad …

Selenium-containing N-heterocyclic carbenes and their first palladium (II) complexes: synthesis, structure, and pendent alkyl chain length dependent catalytic activity …

KN Sharma, H Joshi, AK Sharma, O Prakash… - …, 2013 - ACS Publications
Three new N-alkyl-N′-(2-ethyl-1-selenophenyl) imidazolium salts, L1–L3 (differing in the
chain length of alkyl substituent of N), which are precursors to (Se, CNHC) ligands and their …

Hemilabile and bimetallic coordination in Rh and Ir complexes of NCN pincer ligands

G Mancano, MJ Page, M Bhadbhade… - Inorganic …, 2014 - ACS Publications
Two new pincer ligands have been developed that contain a central N-heterocyclic carbene
(NHC) moiety linked to two pendant pyrazole groups by either a methylene (NCNme) or …

Palladacycles of sulfated and selenated Schiff bases of ferrocene-carboxaldehyde as catalysts for O-arylation and Suzuki–Miyaura coupling

AK Sharma, H Joshi, R Bhaskar, S Kumar… - Dalton …, 2017 - pubs.rsc.org
Schiff base ligands (L1: sulfated and L2: selenated) having a ferrocene core synthesized by
reacting ferrocene-carboxaldehyde with 2-(phenylthio/seleno) ethylamine on treatment with …

Trinuclear complexes of palladium (ii) with chalcogenated N-heterocyclic carbenes: catalysis of selective nitrile–primary amide interconversion and Sonogashira …

P Dubey, S Gupta, AK Singh - Dalton Transactions, 2017 - pubs.rsc.org
3-Methyl-1-(2-(phenylthio/seleno) ethyl)-1H-benzo [d] imidazol-3-ium iodide (L1/L2), a
precursor of sulfated/selenated N-heterocyclic carbene, was synthesized by the reaction of …

Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (κ2-C, S)-thioether-functionalised NHC …

W Chen, J Egly, AI Poblador-Bahamonde… - Dalton …, 2020 - pubs.rsc.org
A series of cationic Ru (II)(η6-p-cymene) complexes with thioether-functionalised N-
heterocyclic carbene ligands have been prepared and fully characterized. Steric and …

Advances in CC coupling reactions catalyzed by homogeneous phosphine free palladium catalysts

LK Mannepalli, C Gadipelly… - Bulletin of the …, 2020 - academic.oup.com
Carbon-carbon coupling reactions are one of the most important systems to be studied and
the design of palladium based phosphine free catalysts is crucial. In this account, we present …