Axially chiral motifs are prominent in chiral ligands and catalysts, natural products, and drug
candidates. Consequently, new strategies for the expedient stereoselective preparation of …

Transition‐metal‐catalyzed direct transformation of inert C− H bond has revolutionized the
arsenal of main‐stream organic synthesis, providing a new upfront to forge structurally …

A highly regio-and stereoselective synthesis of functionalized benzofulvenes via Rh (III)-
catalyzed cascade reactions of benzoyl acetonitrile/methylsulfone/acetate with propargyl …

Metal-catalyzed C–H functionalizations on the aryl ring of anilines usually need
cumbersome N-protection–deprotection strategies to ensure chemoselectivity. We describe …

In recent years, C–C, C–N, and C–O bonds constructed by C–H functionalization have
reached considerable attention due to excellent functional group tolerance, cost …

In this paper, an unprecedented selective synthesis of dihydrophenanthridine and
phenanthridine derivatives through the cascade reactions of 2-arylanilines with alkynoates …

A highly efficient and practical synthesis of benzofulvenes was developed via ketone-
directed Cp* Co (III)-catalyzed sequential C–H activation, addition, cyclization, and …

Unique dual‐emissive and deep‐blue/green fluorescent multi‐substituted 4‐azapyrenes
with bathochromic shift emission, quantum yields up to 0.60 and long excited‐state lifetime …

Herein, we demonstrated a Pd-catalyzed cascade reaction that involves arylation, Trost–
Oppolzer type Alder ene reaction, and double bond isomerization using the 4-(2 …

The reaction of o-benzofulvene with TfOH leads to intramolecular cyclization through novel
C–C and C–N bond formation, resulting in the formation of 5 H, 10′ H-spiro [benzo [k] …