The role of carbonate in catalytic oxidations

SG Patra, A Mizrahi, D Meyerstein - Accounts of Chemical …, 2020 - ACS Publications
Conspectus CO2, HCO3–, and CO32–are present in all aqueous media at pH> 4 if no major
effort is made to remove them. Usually the presence of CO2/HCO3–/CO32–is either …

Redox-active ligands in artificial photosynthesis: a review

T Benkó, D Lukács, M Li, JS Pap - Environmental Chemistry Letters, 2022 - Springer
Given the rising socioeconomic issues of fossil fuels, efficient artificial photosynthesis would
be an important milestone toward a sustainable world. A key step of photosynthesis is the …

Electrocatalytic and photoelectrocatalytic methanol oxidation by cobalt carbonate

I Udachyan, T Zidki, A Mizrahi, SG Patra… - ACS Applied Energy …, 2022 - ACS Publications
Na3CoIII (CO3) 3 was deposited on Pt and Pd electrode surfaces by a chronoamperometric
technique. The deposited Na3CoIII (CO3) 3 was characterized using various surface …

Oxidation Chemistry of Bicarbonate and Peroxybicarbonate: Implications for Carbonate Management in Energy Storage

Z Yan, KG Reynolds, R Sun, Y Shin… - Journal of the …, 2023 - ACS Publications
Carbonate formation presents a major challenge to energy storage applications based on
low-temperature CO2 electrolysis and recyclable metal–air batteries. While direct …

The FeII (citrate) Fenton reaction under physiological conditions

E Illés, SG Patra, V Marks, A Mizrahi… - Journal of Inorganic …, 2020 - Elsevier
Abstract The Fenton reaction of Fe II (citrate) in the presence and absence of bicarbonate
(HCO 3−) is studied. It is found that the rate constant of the Fenton reaction (k obs) increases …

Manganese Carbonate (Mn2(CO3)3) as an Efficient, Stable Heterogeneous Electrocatalyst for the Oxygen Evolution Reaction

I Udachyan, JT Bhanushali, A Mizrahi… - ACS Applied Energy …, 2022 - ACS Publications
With the growing population and energy demand, there is an urgent need for the production
and storage of clean energy obtained from renewable resources. Water splitting …

Heterogeneous Electrocatalytic Oxygen Evolution Reaction by a Sol‐Gel Electrode with Entrapped Na3[Ru2(μ‐CO3)4]: The Effect of NaHCO3

S Aharon, SG Patra, D Meyerstein, E Tzur… - …, 2023 - Wiley Online Library
Abstract The Na3 [Ru2 (μ‐CO3) 4] complex is acting as a water oxidation catalyst in a
homogeneous system. Due to the significance of heterogeneous systems and the effect of …

Facile synthesis of efficient Co 3 O 4 nanostructures using the milky sap of Calotropis procera for oxygen evolution reactions and supercapacitor applications

AL Bhatti, A Tahira, S Kumar, ZA Ujjan, MA Bhatti… - RSC …, 2023 - pubs.rsc.org
The preparation of Co3O4 nanostructures by a green method has been rapidly increasing
owing to its promising aspects, such as facileness, atom economy, low cost, scale-up …

On the mechanism of heterogeneous water oxidation catalysis: A theoretical perspective

SG Patra, D Meyerstein - Inorganics, 2022 - mdpi.com
Earth abundant transition metal oxides are low-cost promising catalysts for the oxygen
evolution reaction (OER). Many transition metal oxides have shown higher OER activity than …

The Catalytic Mechanism of a Highly Active Cobalt Chlorin Complex for Photocatalytic Water Oxidation

T Nakazono, R Mitsuda, K Hashimoto, T Wada… - Inorganic …, 2024 - ACS Publications
Highly active catalysts for electrocatalytic and photocatalytic water oxidation are strongly
demanded to realize artificial photosynthesis. A cobalt complex with a chlorin derivative …