Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

KP Bryliakov - Chemical reviews, 2017 - ACS Publications
The discovery of simple and efficient catalyst systems for the asymmetric
oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this …

Organocatalytic asymmetric epoxidation and aziridination of olefins and their synthetic applications

Y Zhu, Q Wang, RG Cornwall, Y Shi - Chemical Reviews, 2014 - ACS Publications
Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic
Applications | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In …

[HTML][HTML] Rearrangements of organic peroxides and related processes

IA Yaremenko, VA Vil, DV Demchuk… - Beilstein journal of …, 2016 - beilstein-journals.org
This review is the first to collate and summarize main data on named and unnamed
rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides …

Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts

O Cusso, I Garcia-Bosch, X Ribas… - Journal of the …, 2013 - ACS Publications
A non-heme iron complex that catalyzes highly enantioselective epoxidation of olefins with
H2O2 is described. Improvement of enantiomeric excesses is attained by the use of catalytic …

Theory and modeling of asymmetric catalytic reactions

Y Lam, MN Grayson, MC Holland… - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Modern density functional theory and powerful contemporary computers have
made it possible to explore complex reactions of value in organic synthesis. We describe …

Coordinating Ability of Anions, Solvents, Amino Acids, and Gases towards Alkaline and Alkaline‐Earth Elements, Transition Metals, and Lanthanides

S Alvarez - Chemistry–A European Journal, 2020 - Wiley Online Library
After briefly reviewing the applications of the coordination ability indices proposed earlier for
anions and solvents toward transition metals and lanthanides, a new analysis of crystal …

Chemoselective oxidative generation of ortho-quinone methides and tandem transformations

M Uyanik, K Nishioka, R Kondo, K Ishihara - Nature Chemistry, 2020 - nature.com
Abstract ortho-Quinone methides are useful transient synthetic intermediates in organic
synthesis. These species are most often generated in situ by the acid-or base-mediated …

Asymmetric organocatalytic epoxidations: Reactions, scope, mechanisms, and applications

RL Davis, J Stiller, T Naicker, H Jiang… - Angewandte Chemie …, 2014 - Wiley Online Library
Chiral epoxides serve as versatile building blocks in the synthesis of complex organic
frameworks. The high strain imposed by the three‐membered ring system makes epoxides …

Organocatalytic activation of hydrogen peroxide: towards green and sustainable oxidations

E Poursaitidis, PL Gkizis, I TRIANTAFILLIDI… - Chemical …, 2024 - pubs.rsc.org
The advent of organocatalysis provided an additional option in every researcher's arsenal,
towards the development of elegant and sustainable protocols for various organic …

Iron Catalyzed Highly Enantioselective Epoxidation of Cyclic Aliphatic Enones with Aqueous H2O2

O Cusso, M Cianfanelli, X Ribas… - Journal of the …, 2016 - ACS Publications
An iron complex with a C 1-symmetric tetradentate N-based ligand catalyzes the asymmetric
epoxidation of cyclic enones and cyclohexene ketones with aqueous hydrogen peroxide …