This review is concerned with the theoretical and computational modeling of bimolecular
reactions, especially with generally applicable methods for kinetics (ie, overall rates as …

In this review, we present an overview of our recent work on the infrared spectroscopy of
mass-selected gas-phase molecular ions. The ions are stored and isolated in a quadrupole …

We present an overview of the current status of transition-state theory and its
generalizations. We emphasize (i) recent improvements in available methodology for …

We review the current status of transition-state theory. We focus on the validity of its basic
assumptions and of corrections to and improvements of conventional transition-state theory …

We present a method for calculating the infrared emission from a population of dust grains
heated by starlight, including very small grains for which stochastic heating by starlight …

Unimolecular reaction systems in which multiple isomers undergo simultaneous reactions
via multiple decomposition reactions and multiple isomerization reactions are of …

Abstract Cyclic Ethers (CEs) belong to a class of compounds of importance to understand
the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of …

Theoretical expressions for the strong collision rate constants of thermal unimolecular
reactions at low pressures k 0sc are discussed. The rate constant is split up into various …

Analysis of the energy dependence of the cross sections for collision-induced dissociation
reactions has permitted the determination of quantitative thermodynamic information for a …

Chemical kinetics is central in much of tropospheric chemistry and in modeling tropospheric
chemical processes. Chemical reaction rate coefficients and product yields have traditionally …