At the advent of cross-coupling chemistry, carbon electrophiles based on halides or
pseudohalides were the only suitable electrophilic coupling partners. Almost two decades …

This Review examines parts per million (ppm) palladium concentrations in catalytic cross-
coupling reactions and their relationship with mole percentage (mol%). Most studies in …

Organosilicon compounds act as a nucleophile upon activation by an appropriate base and
behave in a manner similar to main-group organometallic reagents. In the last decades …

Abstract Transition-metal-catalysed, redox-neutral dehydrosilylation of alkenes is a long-
standing challenge in organic synthesis, with current methods suffering from low selectivity …

The aryl-substituted bis (imino) pyridine cobalt methyl complex,(MesPDI) CoCH3 (MesPDI=
2, 6-(2, 4, 6-Me3C6H2-N CMe) 2C5H3N), promotes the catalytic dehydrogenative …

We report here a new method for the synthesis of organohydrosilanes from phenols and
ketones. This method is established through reductive C− Si coupling of chlorohydrosilanes …

Herein, we report a regioselective alkenyl electrophile synthesis from unactivated olefins
that is based on a direct and regioselective C− H thianthrenation reaction. The selectivity is …

The cross‐electrophile coupling has become a powerful tool for C− C bond formation, but its
potential for forging the C− Si bond remains unexplored. Here we report a cross‐electrophile …

An efficient cross-electrophile couplings of aryl fluorosulfates with vinyl chlorosilanes by
using nickel as transition metal catalyst and manganese as reductant has been achieved …

Cross-electrophile C–Si coupling has emerged as a promising tool for the construction of
organosilanes, but the potential of this method remains largely unexplored. Herein, we …