Cyclotrimetaphosphate-assisted ruthenium catalyst for the hydration of nitriles and oxidation of primary amines to amides under aerobic conditions in water
KK Chouhan, D Chowdhury… - Organic & Biomolecular …, 2023 - pubs.rsc.org
Amide bonds are ubiquitous and regarded as an essential constituent of many biologically
active drug molecules and fine chemicals. We report a practical and operationally simple …
active drug molecules and fine chemicals. We report a practical and operationally simple …
Electrocatalytic Anaerobic Oxidation of Benzylic Amines Enabled by Ferrocene-Based Redox Mediators
AL Waldbusser, S Hematian - Organometallics, 2024 - ACS Publications
The generation and functionalization of carbon-or nitrogen-centered radicals are of great
interest for their potential synthetic utility. Here, we report the anaerobic electrocatalytic …
interest for their potential synthetic utility. Here, we report the anaerobic electrocatalytic …
Synthesis of primary amides by a one-pot reaction of ammonia gas with esters or tertiary amides
XY Li, JX Kang, YN Ma, X Chen - Cell Reports Physical Science, 2024 - cell.com
Relative to secondary or tertiary amides, the synthesis of primary amides is more
challenging because only a few nitrogen sources, such as NH 3, NH 2−, and others, can be …
challenging because only a few nitrogen sources, such as NH 3, NH 2−, and others, can be …
Phenalenyl-ruthenium synergism for effectual catalytic transformations of primary amines to amides
N Bandopadhyay, K Paramanik, G Sarkar, S Roy… - Dalton …, 2024 - pubs.rsc.org
The synthesis of amides holds great promise owing to their impeccable contributions as
building blocks for highly valued functional derivatives. Herein, we disclose the design …
building blocks for highly valued functional derivatives. Herein, we disclose the design …
Half‐sandwich Ru (II) complexes: Effect of ligands on aerobic oxidation of benzylamine
O Moždiak, P Dubey, L Dostál… - Applied …, 2023 - Wiley Online Library
In this study, we compared carbene and pyridine substituted ligands {3‐Me‐1‐[2‐
(CH2CH2SPh)]‐C7H4N2}(L1) and {2‐[(2, 6‐iPr2‐C6H3) N= CH]‐6‐(MeO) C5H3N}(L2) for …
(CH2CH2SPh)]‐C7H4N2}(L1) and {2‐[(2, 6‐iPr2‐C6H3) N= CH]‐6‐(MeO) C5H3N}(L2) for …
A new facet of amide synthesis by tandem acceptorless dehydrogenation of amines and oxygen transfer of DMSO
X Nie, M Wang, Y Fu, J Xu, X Zheng, H Chen, Z Su… - Journal of …, 2023 - Elsevier
We have developed a new catalytic system for preparing amides by tandem acceptorless
dehydrogenation of amines and oxygen transfer of DMSO. This system shows very good …
dehydrogenation of amines and oxygen transfer of DMSO. This system shows very good …
Heteroleptic ruthenium (ii) complexes featuring N-heterocyclic carbene-based C^ N donor sets for solar energy conversion
We present a series of heteroleptic ruthenium (II) complexes featuring N-heterocyclic
carbene-based C^ N donor sets functionalized with long hydrophobic chains (ndecyl and …
carbene-based C^ N donor sets functionalized with long hydrophobic chains (ndecyl and …
Switchable activity of a Ru catalyst bearing an annulated mesoionic carbene ligand for oxidation of primary amines
The catalytic activity of a Ru complex 1, bearing a fused π‐conjugated imidazo [1, 2–a][1, 8]
naphthyridine‐based mesoionic carbene (MIC) ligand, is examined for the oxidation of …
naphthyridine‐based mesoionic carbene (MIC) ligand, is examined for the oxidation of …
Structural, Electrochemical and Catalytic Elucidation of Cyclooctadiene Ru(II)‐Nitrile Complexes of the Type [RuCl2(cod)(NCR)2]
FP Malan - ChemistrySelect, 2022 - Wiley Online Library
The facile synthesis of a range of eleven cyclooctadiene Ru (II) complexes of the type
[RuCl2 (cod)(NCR) 2] featuring different nitrile ligands using two synthetic routes is reported …
[RuCl2 (cod)(NCR) 2] featuring different nitrile ligands using two synthetic routes is reported …