Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Substituted and annulated pyrroles containing chiral centers are potentially accessible by
means of an organocatalytic enantioselective Friedel‐Crafts alkylation (FCA) reaction. They …

Described herein is a chiral magnesium bisphosphate-catalyzed asymmetric double C (sp3)–
H bond functionalization triggered by a sequential hydride shift/cyclization process. This …

A catalytic and highly enantioselective Mukaiyama–Michael addition of difluoroenoxysilanes
to azadienes has been developed using perfluorinated aryl-incorporating chiral …

This work describes new chiral task-specific ionic liquids bearing chiral anions as the
catalysts for the enantioselective multicomponent Biginelli reaction. For the first time, the …

The use of more than one catalyst in one-pot reaction conditions has become a rapidly
evolving protocol in the development of asymmetric catalysis. The lack of molecular insights …

Dienes are prevalent substructures in biologically active molecules and versatile building
blocks in synthetic chemistry. Herein, using Lewis acids promoted dual 1, 3‐sulfur …

In recent years, the field of organocatalysis has extensively explored the use of carbenium
ions for practical C− C bond forming reactions. In order to control the formation of new …

Methods for the modification of indole derivatives are powerful techniques in organic,
medicinal, and biomolecular chemistry. Here, we report a protocol for the C–H alkenylation …

Among the fundamental chemical transformations in organic synthesis, rearrangement has
been recognized as powerful and reliable reactions for the construction of carbon–carbon or …