Carbon oxygenate transformations by actinide compounds and catalysts

PL Arnold, ZR Turner - Nature Reviews Chemistry, 2017 - nature.com
Carbon oxygenates represent an increasingly important class of feedstock in the
development of a sustainable chemical economy. Their catalytic transformation into value …

Organometallic neptunium chemistry

PL Arnold, MS Dutkiewicz, O Walter - Chemical Reviews, 2017 - ACS Publications
Fifty years have passed since the foundation of organometallic neptunium chemistry, and yet
only a handful of complexes have been reported, and even fewer have been fully …

N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners

CAP Goodwin, RW Adams, AJ Gaunt… - Journal of the …, 2024 - ACS Publications
Comparison of bonding and electronic structural features between trivalent lanthanide (Ln)
and actinide (An) complexes across homologous series' of molecules can provide insights …

Recent studies of the synthesis, functionalization, optoelectronic properties and applications of dibenzophospholes

P Hibner-Kulicka, JA Joule, J Skalik, P Bałczewski - RSC advances, 2017 - pubs.rsc.org
The first dibenzophospholes were described in the 1950s, but only recently have they
gained greater importance, due to their use in organic electronics and the possibility of …

The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds

SE Gilson, PC Burns - Coordination Chemistry Reviews, 2021 - Elsevier
Structures of 388 neptunium-bearing crystal structures are sorted into an expanded
structural hierarchy and examined. The majority of structures contain Np (V)(149), Np …

Molecular actinide compounds with soft chalcogen ligands

M Ephritikhine - Coordination Chemistry Reviews, 2016 - Elsevier
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Stable Chelation of the Uranyl Ion by Acyclic Hexadentate Ligands: Potential Applications for 230U Targeted α-Therapy

JJ Woods, R Unnerstall, A Hasson, DS Abou… - Inorganic …, 2022 - ACS Publications
Uranium-230 is an α-emitting radionuclide with favorable properties for use in targeted α-
therapy (TAT), a type of nuclear medicine that harnesses α particles to eradicate cancer …

Comparing the 2, 2′‐Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium

JN Cross, JA Macor, JA Bertke, MG Ferrier… - Angewandte …, 2016 - Wiley Online Library
Advancing our understanding of the minor actinides (Am, Cm) versus lanthanides is key for
developing advanced nuclear‐fuel cycles. Herein, we describe the preparation of (NBu4) …

Coordination Chemistry and QTAIM Analysis of Homoleptic Dithiocarbamate Complexes, M(S2CNiPr2)4 (M = Ti, Zr, Hf, Th, U, Np)

AC Behrle, AJ Myers, A Kerridge… - Inorganic …, 2018 - ACS Publications
In a systematic approach to comparing the molecular structure and bonding in homoleptic
transition-metal and actinide complexes, a series of dithiocarbamates, M (S2CNiPr2) 4 (M …

Chromium N-phosphinoamidine ethylene tri-/tetramerization catalysts: Designing a step change in 1-octene selectivity

T Ogawa, F Lindeperg, M Stradiotto, L Turculet… - Journal of …, 2021 - Elsevier
Steric reduction principles were applied in N-phosphinoamidine ligand (PN) design to
significantly improve 1-octene selectivity in ethylene tri-/tetramerization chromium catalysis …