Carbodiimide-based synthesis of N-heterocycles: moving from two classical reactive sites to chemical bond breaking/forming reaction

Y Wang, WX Zhang, Z Xi - Chemical Society Reviews, 2020 - pubs.rsc.org
Carbodiimides are a unique class of heterocumulene compounds that display distinctive
chemical properties. The rich chemistry of carbodiimides has drawn increasing attention …

Metal nanoparticles in ionic liquids

S Wegner, C Janiak - Topics in Current Chemistry, 2017 - Springer
During the last years ionic liquids (ILs) were increasingly used and investigated as reaction
media, hydrogen sources, catalysts, templating agents and stabilizers for the synthesis of …

Mechanochemical Release of N‐Heterocyclic Carbenes from Flex‐Activated Mechanophores

H Shen, MB Larsen, AG Roessler… - Angewandte …, 2021 - Wiley Online Library
We have discovered a new flex‐activated mechanophore that releases an N‐heterocyclic
carbene (NHC) under mechanical load. The mechanophore design is based upon NHC …

Uniform Ru nanoparticles on N-doped graphene for selective hydrogenation of fatty acids to alcohols

LM Martínez-Prieto, M Puche, C Cerezo-Navarrete… - Journal of …, 2019 - Elsevier
Abstract Ruthenium nanoparticles (Ru NPs) supported on reduced-graphene oxide doped
with N (NH 2-rGO) was synthesized and used for the selective hydrogenation of fatty acids to …

Organometallic ruthenium nanoparticles: synthesis, surface chemistry, and insights into ligand coordination

LM Martínez-Prieto, B Chaudret - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Although there has been for the past 20 years great interest in the synthesis and
use of metal nanoparticles, little attention has been paid to the complexity of the surface of …

Controlled metal nanostructures: Fertile ground for coordination chemists

C Amiens, D Ciuculescu-Pradines… - Coordination Chemistry …, 2016 - Elsevier
Composition (metal or metal oxide core and organic coating), size, shape and structure are
the main parameters governing the properties of nano-objects. Driven by their huge …

N-Heterocyclic Carbene-Carbodiimide (NHC-CDI) Betaines as Organocatalysts for β-Butyrolactone Polymerization: Synthesis of Green PHB Plasticizers with Tailored …

D Sanchez-Roa, V Sessini, MEG Mosquera… - ACS …, 2024 - ACS Publications
The manufacture of poly (3-hydroxybutyrate)(PHB) stands out as a promising alternative to
traditional plastics. This polymer is usually produced by bacteria-based biotechnology or …

Stainless steel-mediated hydrogen generation from alkanes and diethyl ether and its application for arene reduction

Y Sawama, N Yasukawa, K Ban, R Goto… - Organic …, 2018 - ACS Publications
Hydrogen gas can be generated from simple alkanes (eg, n-pentane, n-hexane, etc.) and
diethyl ether (Et2O) by mechanochemical energy using a planetary ball mill (SUS304 …

High diversity of microalgae as a tool for the synthesis of different silver nanoparticles: A species-specific green synthesis

LC Moraes, RC Figueiredo, R Ribeiro-Andrade… - Colloid and Interface …, 2021 - Elsevier
Autotrophic microorganisms can be useful for the green synthesis of nanoparticles (NPs),
but there is a lack of knowledge to affirm if the high variety of microorganisms is connected to …

Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions

LM Martínez-Prieto, A Ferry, L Rakers… - Chemical …, 2016 - pubs.rsc.org
The synthesis and catalytic activity of long-chain NHC-stabilized RuNPs are presented. Full
characterization of these novel nanostructures including surface state studies show that the …