The Buchwald–Hartwig amination after 25 years

R Dorel, CP Grugel, AM Haydl - … Chemie International Edition, 2019 - Wiley Online Library
The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …

Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

Applications of palladium-catalyzed C–N cross-coupling reactions

P Ruiz-Castillo, SL Buchwald - Chemical reviews, 2016 - ACS Publications
Pd-catalyzed cross-coupling reactions that form C–N bonds have become useful methods to
synthesize anilines and aniline derivatives, an important class of compounds throughout …

Interfacing single-atom catalysis with continuous-flow organic electrosynthesis

MA Bajada, J Sanjosé-Orduna, G Di Liberto… - Chemical Society …, 2022 - pubs.rsc.org
The global warming crisis has sparked a series of environmentally cautious trends in
chemistry, allowing us to rethink the way we conduct our synthesis, and to incorporate more …

Photoredox catalysis in organic chemistry

MH Shaw, J Twilton… - The Journal of organic …, 2016 - ACS Publications
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a
powerful strategy for the activation of small molecules. In a general sense, these approaches …

Selected Copper‐Based Reactions for C− N, C− O, C− S, and C− C Bond Formation

S Bhunia, GG Pawar, SV Kumar… - Angewandte Chemie …, 2017 - Wiley Online Library
Metal‐catalyzed cross‐coupling reactions belong to the most important transformations in
organic synthesis. Copper catalysis has received great attention owing to the low toxicity …

N-Aryl–linked spirocyclic polymers for membrane separations of complex hydrocarbon mixtures

KA Thompson, R Mathias, D Kim, J Kim, N Rangnekar… - Science, 2020 - science.org
The fractionation of crude-oil mixtures through distillation is a large-scale, energy-intensive
process. Membrane materials can avoid phase changes in such mixtures and thereby …

Aryl amination using ligand-free Ni (II) salts and photoredox catalysis

EB Corcoran, MT Pirnot, S Lin, SD Dreher, DA DiRocco… - Science, 2016 - science.org
Over the past two decades, there have been major developments in transition metal–
catalyzed aminations of aryl halides to form anilines, a common structure found in drug …

Palladium‐catalyzed cross‐coupling: a historical contextual perspective to the 2010 Nobel Prize

CCC Johansson Seechurn, MO Kitching… - Angewandte Chemie …, 2012 - Wiley Online Library
Abstract In 2010, Richard Heck, Ei‐ichi Negishi, and Akira Suzuki joined the prestigious
circle of Nobel Laureate chemists for their roles in discovering and developing highly …

Palladium catalysis enables cross-coupling–like SN2-glycosylation of phenols

LF Deng, Y Wang, S Xu, A Shen, H Zhu, S Zhang… - Science, 2023 - science.org
Despite their importance in life and material sciences, the efficient construction of stereo-
defined glycosides remains a challenge. Studies of carbohydrate functions would be …