Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J Li, CA Triana, W Wan, DPA Saseendran… - Chemical Society …, 2021 - pubs.rsc.org
The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

Molecular catalysts for water oxidation

JD Blakemore, RH Crabtree, GW Brudvig - Chemical Reviews, 2015 - ACS Publications
The development of technologies for the production of chemical fuels or useful compounds
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …

[PDF][PDF] Recent advances in catalysts based on molecular cubanes for visible light-driven water oxidation

W Sun, J Lin, X Liang, J Yang, B Ma… - Acta Phys.-Chim. Sin …, 2020 - whxb.pku.edu.cn
Increasing climate change and environmental pollution caused by the excessive use of
fossil fuels have prompted intensive research into clean and efficient renewable sources as …

Coordination Geometry and Oxidation State Requirements of Corner-Sharing MnO6 Octahedra for Water Oxidation Catalysis: An Investigation of Manganite (γ …

PF Smith, BJ Deibert, S Kaushik, G Gardner… - ACS …, 2016 - ACS Publications
Surface-directed corner-sharing MnO6 octahedra within numerous manganese oxide
compounds containing Mn3+ or Mn4+ oxidation states show strikingly different catalytic …

Water Oxidation Catalysis by Co(II) Impurities in Co(III)4O4 Cubanes

AM Ullman, Y Liu, M Huynh, DK Bediako… - Journal of the …, 2014 - ACS Publications
The observed water oxidation activity of the compound class Co4O4 (OAc) 4 (Py–X) 4
emanates from a Co (II) impurity. This impurity is oxidized to produce the well-known Co …

3d–4f {CoII3Ln(OR)4} Cubanes as Bio-Inspired Water Oxidation Catalysts

F Evangelisti, R Moré, F Hodel, S Luber… - Journal of the …, 2015 - ACS Publications
Although the {CaMn4O5} oxygen evolving complex (OEC) of photosystem II is a major
paradigm for water oxidation catalyst (WOC) development, the comprehensive translation of …

{Co4O4} and {CoxNi4–xO4} Cubane Water Oxidation Catalysts as Surface Cut-Outs of Cobalt Oxides

F Song, R Moré, M Schilling… - Journal of the …, 2017 - ACS Publications
The future of artificial photosynthesis depends on economic and robust water oxidation
catalysts (WOCs). Cobalt-based WOCs are especially promising for knowledge transfer …

Mechanistic Aspects of Cobalt–Oxo Cubane Clusters in Oxidation Chemistry

J Amtawong, AI Nguyen, TD Tilley - Journal of the American …, 2022 - ACS Publications
Cobalt oxides are recognized as one of the most efficient earth-abundant catalysts for
challenging oxidation chemistry, with substrates ranging from water to organic compounds …

X-ray Spectroscopic Characterization of Co(IV) and Metal–Metal Interactions in Co4O4: Electronic Structure Contributions to the Formation of High-Valent States …

RG Hadt, D Hayes, CN Brodsky… - Journal of the …, 2016 - ACS Publications
The formation of high-valent states is a key factor in making highly active transition-metal-
based catalysts of the oxygen evolution reaction (OER). These high oxidation states will be …

Structural basis for differing electrocatalytic water oxidation by the cubic, layered and spinel forms of lithium cobalt oxides

G Gardner, J Al-Sharab, N Danilovic, YB Go… - Energy & …, 2016 - pubs.rsc.org
The two polymorphs of lithium cobalt oxide, LiCoO2, present an opportunity to contrast the
structural requirements for reversible charge storage (battery function) vs. catalysis of water …